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Simakin Alexander, Salova Tamara, Devyatova Vera, Zelensky Michael Reduced carbonic fluid and possible nature of high-K magmas of Tolbachik // Journal of Volcanology and Geothermal Research. 2015. V. 307. P. 210 - 221. doi: 10.1016/j.jvolgeores.2015.10.018.    Аннотация
Abstract Historical basaltic eruptions of Tolbachik volcano (Kamchatka) are of a medium to high potassic type. The potassic character of magmatism can be attributed to the influence of CO2–CO-rich fluid at or near the magma generation depths. Decarbonatization reactions in the mantle under Tolbachik producing a column of the carbonic fluids may be connected with the recent accretion of Kronotsky paleoarc with carbonates dragged under the mantle wedge. With thermodynamic modeling, we show that reduced carbonic fluid at fO2 < {NNO} may be a good carrier of nickel transported in the form of Ni(CO)4. This carbonyl is expected to become thermally stable near the magmatic temperatures at pressures above 1 GPa. In the crust, it is predicted to be thermally stable within the {PT} field of the amphibolite facies. We connect the particles of native Ni and Ag–Pt alloy observed in the volcanic aerosols from the 2012–13 Tolbachik eruption with flushing of the ascending Tolbachik magma with reduced carbonic fluids enriched with {PGE} and Ni. Native metals may form by the thermal decomposition of the carbonyls and other carbon-bearing compounds dissolved in the fluid.
Simon A., Yogodzinski G.M., Robertson K., Smith E., Selyangin O., Kiryukhin A., Mulcahy S.R., Walker J.D. Evolution and genesis of volcanic rocks from Mutnovsky Volcano, Kamchatka // Journal of Volcanology and Geothermal Research. 2014. V. 286. P. 116 - 137. doi: 10.1016/j.jvolgeores.2014.09.003.    Аннотация
This study presents new geochemical data for Mutnovsky Volcano, located on the volcanic front of the southern portion of the Kamchatka arc. Field relationships show that Mutnovsky Volcano is comprised of four distinct stratocones, which have grown over that past 80 ka. The youngest center, Mutnovsky IV, has produced basalts and basaltic andesites only. The three older centers (Mutnovsky I, II, III) are dominated by basalt and basaltic andesite (60–80 by volume), but each has also produced small volumes of andesite and dacite. Across centers of all ages, Mutnovsky lavas define a tholeiitic igneous series, from 48–70 SiO2. Basalts and basaltic andesites have relatively low K2O and Na2O, and high FeO* and Al2O3 compared to volcanic rocks throughout Kamchatka. The mafic lavas are also depleted in the light rare earth elements (REEs), with chondrite-normalized La/Sm < 1.0. Andesites have generally higher REE abundances and are more enriched in light REEs, some showing negative Eu anomalies. All samples are depleted in field strength elements (HFSEs) relative to similarly incompatible REEs (e.g., low La/Ta, Nd/Hf compared to MORB), similar to island arc volcanic rocks worldwide. Radiogenic isotope ratios (Sr, Nd, Pb, Hf) are similar for samples from all four eruptive centers, and indicate that all samples were produced by melting of a similar source mixture. No clear age-progressive changes are evident in the compositions of Mutnovsky lavas. Mass balance and assimilation-fractional crystallization (AFC) modeling of major and rare earth elements (REEs) indicate that basaltic andesites were produced by FC of plagioclase, clinopyroxene and olivine from a parental basalt, combined with assimilation of a melt composition similar to dacite lavas present at Mutnovsky. This modeling also indicates that andesites were produced by FC of plagioclase from basaltic andesite, combined with assimilation of dacite. Dacites erupted from Mutnovsky I and II have low abundances of REEs, and do not appear to be related to mafic magmas by FC or AFC processes. These dacites are modeled as the products of dehydration partial melting at mid-crustal levels of a garnet-free, amphibole-bearing basaltic rock, which itself formed in the mid-crust by emplacement of magma that originated from the same source as all Mutnovsky magmas. Lead isotope data indicate that subducted sediment is likely present in the source beneath Mutnovsky and most Kamchatka volcanoes, but uniformly radiogenic Hf and Nd in mafic samples (εNd = 8.7–9.3, εHf = 15.4–15.9), and significant variation in trace element ratios at nearly constant εNd and εHf, indicate that sediment plays a minor roll in controlling subduction trace element patterns in Mutnovsky lavas. Mafic lavas with Ba/Th > 450 require an aqueous fluid source component from subducting oceanic crust, but mixing patterns in isotope versus trace element ratio plots for Hf and the REEs (εNd and εHf vs. ratios with Ce, Nd and Hf) demonstrate that a source component with radiogenic Nd and Hf, and fractionated (arc-type) trace element ratios must be present in the source of Mutnovsky lavas. This source component, which is interpreted to be a partial melt of subducted basalt in the eclogite facies (eclogite melt source component), appears to be present in the source of all Kamchatka volcanoes. Cross-arc geochemical patterns at Mutnovsky and in other arc systems (Isu-Bonin, Tonga-Kermadec) suggest that the aqueous fluid component diminishes and the eclogite melt component is increased from volcanoes at the arc front compared to those in rear-arc positions.
Slezin Yu.B. The Bezymyannyi, Shiveluch, and St. Helens volcanoes: A comparative revision of their catastrophic eruptions during the 20th century // Journal of Volcanology and Seismology. 2015. V. 9. № 5. P. 289-294. doi:10.1134/S0742046315050073.
Slezin Yu.B. The morphology and rheology of modern Klyuchevskoi parasitic lava flows // Volcanology and Seismology. 1990. V. 10. V. 5. P. 665-686.
Sorokin A.A., Girina O.A., Korolev S.P., Romanova I.M., Efremov V.Yu., Malkovskii S., Verkhoturov A., Balashov I. The system of computer modeling of ash cloud propagation from Kamchatka volcanoes // 2016 6th International Workshop on Computer Science and Engineering (WCSE 2016). Tokyo, Japan: 2016. V. II. P. 730-733.
Sorokin A.A., Girina O.A., Loupian E.A., Malkovskii S.I., Balashov I.V., Efremov V.Yu., Kramareva L.S., Korolev S.P., Romanova I.M., Simonenko E.V. Satellite observations and numerical simulation results for the comprehensive analysis of ash clouds transport during the explosive eruptions of Kamchatka volcanoes // Russian Meteorology and Hydrology. 2017. V. 42. № 12. P. 759-765. doi: 10.3103/S1068373917120032.    Аннотация
Ash clouds resulting from explosive volcanic eruptions pose a real threat to human (for aircraft flights, airports operations, etc.); therefore, the detection, monitoring, and forecast of their movement is an urgent and important issue. The features and examples of application of the new tool developed on the basis of "Monitoring of active volcanoes of Kamchatka and the Kurile Islands" information system (VolSatView) are described. It allows the integrated monitoring and forecasting of ash cloud transport using the data of remote sensing and mathematical modeling as well as the assessment of the parameters of explosive events.
Sorokin A.A., Korolev S.P., Romanova I.M., Girina O.A., Urmanov I.P. RESTful Web Service for Kamchatka Volcanoes Observations // Modern Information Technologies in Earth Sciences. Proceedings of the International Conference. September 8-13, 2014, Petropavlovsk-Kamchatsky. Vladivostok: Dalnauka. 2014. P. 155
Sorokin A.A., Korolev S.P., Romanova I.M., Girina O.A., Urmanov I.P. The Kamchatka volcano video monitoring system // 2016 6th International Workshop on Computer Science and Engineering (WCSE 2016). Tokyo, Japan: 2016. V. II. P. 734-737.
Tanakadate H. Morphological Development of the Volcanic Islet Taketomi in the Kuriles // Proceedings of the Imperial Academy. 1934. V. 10. № 8. P. 494-497. doi: 10.2183/pjab1912.10.494.
Taran Yu.A., Hedenquist J.W., Korzhinsky M.A., Tkachenko S.I., Shmulovich K.I. Geochemistry of magmatic gases from Kudryavy volcano, Iturup, Kuril Islands // Geochimica et Cosmochimica Acta. 1995. V. 59. № 9. P. 1749 - 1761. doi: 10.1016/0016-7037(95)00079-F.    Аннотация
Volcanic vapors were collected during 1990–1993 from the summit crater of Kudryavy, a basaltic andesite volcano on Iturup island in the Kuril arc. The highest temperature (700–940°C) fumarolic discharges are water rich (94–98 mole% H2O and have δD values of −20 to −12%o. The chemical and water isotope compositions of the vapors (temperature of thirteen samples, 940 to 130°C) show a simple trend of mixing between hot magmatic fluid and meteoric water; the magmatic parent vapor is similar in composition to altered seawater. The origin of this endmember is not known; it may be connate seawater, or possibly caused by the shallow incorporation of seawater into the magmatic-hydrothermal system. Samples of condensed vapor from 535 to 940°C fumaroles have major element trends indicating contamination by wall-rock particles. However, the enrichment factors (relative to the host rock) of many of the trace elements indicate another source; these elements likely derive from a degassing magma. The strongest temperature dependence is for Re, Mo, W, Cu, and Co; highly volatile elements such as Cl, I, F, Bi, Cd, B, and Br show little temperature dependence. The Re abundance in high-temperature condensates is 2–10 ppb, sufficient to form the pure Re sulfide recently discovered in sublimates of Kudryavy. Anomalously high I concentrations (1–12 ppm) may be caused by magma-marine sediment interaction, as Br/I ratios are similar to those in marine sediments.

The high-temperature (>700°C) fumaroles have a relatively constant composition (∼2 mol% each C and S species, with SO2/H2S ratio of about 3:1, and 0.5 mol% HCl); as temperature decreases, both St and CI are depleted, most likely due to formation of native S and HCl absorption by condensed liquid, in addition to the dilution by meteoric water. Thermochemical evaluation of the high-temperature gas compositions indicates they are close to equilibrium mixtures, apart from minor loss of H2O and oxidation of CO and H2 during sampling. Calculation to an assumed equilibrium state indicates temperatures from 705 to 987°C. At high temperature (≈900°C), the redox states are close to the overlap of mineral (quartz-fayalite-magnetite and nickel-nickel oxide) and gas (H2OH2SO2H2S) buffer curves, due to heterogeneous reaction between the melt and gas species. At lower temperatures (<800°C), the trend of the redox state is similar to the gas buffer curve, probably caused by homogeneous reaction among gas species in a closed system during vapor ascent.
Taran Yu.A., Pilipenko V.P., Rozhkov A.M., Vakin E.A. A geochemical model for fumaroles of the Mutnovsky volcano, Kamchatka, USSR // Journal of Volcanology and Geothermal Research. 1992. V. 49. № 3–4. P. 269 - 283. doi: 10.1016/0377-0273(92)90018-9.    Аннотация
On the basis of the chemical, isotopic and thermodynamic characteristics of fluids sampled between 1964 and 1989 a genetic model description is given for fumaroles of the Mutnovsky volcano. There are three individual groups of fumaroles in the Mutnovsky crater which show stable activity for a long period of time: “the Active Funnel” (temperatures exceed 600°C), the “Upper Field” (up to 320°C) and the “Bottom Field” (from 100 to 150°C). The three principal zones of emission have different gas composition, water isotopic composition, radioactivity and 3He/4He ratios. The abundance of magmatic components in the high-temperature fumaroles of the “Active Funnel” is much higher than those in gases from the other groups. Emission rate of SO2 from the “Active Funnel” is about 200 t/d, which requires complete degassing as a minimum of 1 km3 of magma every 20 years. Fluids of the “Upper Field” contain up to 80% of steam from the Mutnovsky geothermal system. Temperature variations of the “Bottom Field” fumaroles (from 97°C before 1982 to 151°C in 1989) result from changes in hydrological conditions in the crater. Evaporation of high-saline acid brine which is formed in the interior of the volcano is responsible for the composition of the “Bottom Field” gas-steam discharges.
Taran Yu.A., Rozhkov A.M., Serafimova E.K., Esikov A.D. Chemical and isotopic composition of magmatic gases from the 1988 eruption of Klyuchevskoy volcano, Kamchatka // Journal of Volcanology and Geothermal Research. 1991. V. 46. № 3–4. P. 255 - 263. doi: 10.1016/0377-0273(91)90087-G.    Аннотация
Gas samples have been collected at the place of magma effusion during the 1988 flank eruption of Klyuchevskoy, for the first time in the course of studies at this volcano. The high-temperature gases (1000–1100°C) are rich in water and halogens but depleted in sulphur. Their molar composition is close to chemical equilibrium at the collection temperature, while their oxidation state corresponds to redox conditions between FMO and NNO buffers. The isotopic composition of the water (δD = −71 to −44‰; δ18O = +6.3 to +8.4‰, versus SMOW) plots within the field of “primary magmatic” waters. The isotopic composition of H2 (δD = −187‰ to −160‰) is consistent with isotopic equilibrium between H2 and H2O in the conditions of emission. Both the chemistry of the gases and the low δ13C of carbon dioxide (−11.6‰, PDB) suggest extensive magma outgassing occurred during the course of the eruption.
Taran Yuri, Inguaggiato Salvatore, Cardellini Carlo, Karpov Gennady Posteruption chemical evolution of a volcanic caldera lake: Karymsky Lake, Kamchatka // Geophysical Research Letters. 2013. V. 40. № 19. P. 5142-5146. doi:10.1002/grl.50961.    Аннотация
The 1996 short-lived subaqueous eruption at the Karymsky caldera lake suddenly changed the composition of the lake water. The lake, with a surface area of ∼10 km^2 and a volume of ∼0.5 km^3, became acidic, increased its salinity to ∼1000 mg/kg, and became dominated by SO4^2- and Ca^2+. Since the eruption, the lake chemistry has evolved in a predictable manner described by simple box model. As a result of dilution by incoming SO4-Ca-Mg-poor water, SO4, Ca, and Mg concentrations follow a simple exponential decrease with a characteristic time close to the residence time of the lake. Na, K, and Cl decrease relatively significantly slower, indicating a continuing input of these constituents into the lake that was initiated during the eruption. Thus, the dynamics of two groups of lake water solutes can be predicted by a simple box model for water and solute mass balance. Key Points Karymsky lake suddenly changed chemistry as a result of the 1996 eruption One-box dynamic model correctly describes the evolution of the lake chemistry The calculated fluxes of chemicals are in a good agreement with the field data
Taran Yuri, Yurova L.M. The origin of SO4-Cl acidic brines from the Baransky geothermal field, Kuriles // XIX International Geology Congress. , Kyoto, Japan. 1992. P. 10
Taran Yuri, Yurova L.M. Volcanic-hydrothermal system of Baransky volcano, Iturup, Kurile islands // IUGG XXI General Assembley. 1995. P. VA41C - 6.
Taran Yuri, Zelenski Mikhail, Chaplygin Ilya, Malik Natalia, Campion Robin, Inguaggiato Salvatore, Pokrovsky Boris, Kalacheva Elena, Melnikov Dmitry, Kazahaya Ryunosuke, Fischer Tobias Gas Emissions From Volcanoes of the Kuril Island Arc (NW Pacific): Geochemistry and Fluxes // Geochemistry, Geophysics, Geosystems. 2018. V. 19. V. 6. P. 1859-1880. doi: 10.1029/2018GC007477.    Аннотация
The Kuril Island arc extending for about 1,200 km from Kamchatka Peninsula to Hokkaido Island is a typical active subduction zone with ∼40 historically active subaerial volcanoes, some of which are persistently degassing. Seven Kurilian volcanoes (Ebeko, Sinarka, Kuntomintar, Chirinkotan, Pallas, Berg, and Kudryavy) on six islands (Paramushir, Shiashkotan, Chirinkotan, Ketoy, Urup, and Iturup) emit into the atmosphere > 90% of the total fumarolic gas of the arc. During the field campaigns in 2015–2017 direct sampling of fumaroles, MultiGas measurements of the fumarolic plumes and DOAS remote determinations of the SO2 flux were conducted on these volcanoes. Maximal temperatures of the fumaroles in 2015–2016 were 510°C (Ebeko), 440°C (Sinarka), 260°C (Kuntomintar), 720°C (Pallas), and 820°C (Kudryavy). The total SO2 flux (in metric tons per day) from fumarolic fields of the studied volcanoes was measured as ∼1,800 ± 300 t/d, and the CO2 flux is estimated as 1,250 ± 400 t/d. Geochemical characteristics of the sampled gases include δD and δ18O of fumarolic condensates, δ13C of CO2, δ34S of the total sulfur, ratios 3He/4He and 40Ar/36Ar, concentrations of the major gas species, and trace elements in the volcanic gas condensates. The mole ratios C/S are generally <1. All volcanoes of the arc, except the southernmost Mendeleev and Golovnin volcanoes on Kunashir Island, emit gases with 3He/4He values of >7RA (where RA is the atmospheric 3He/4He). The highest 3He/4He ratios of 8.3RA were measured in fumaroles of the Pallas volcano (Ketoy Island) in the middle of the arc.
Telling J., Flower V.J.B., Carn S.A. A multi-sensor satellite assessment of SO2 emissions from the 2012–13 eruption of Plosky Tolbachik volcano, Kamchatka // Journal of Volcanology and Geothermal Research. 2015. V. 307. P. 98 - 106. doi: 10.1016/j.jvolgeores.2015.07.010.    Аннотация
Abstract Prolonged basaltic effusive eruptions at high latitudes can have significant atmospheric and environmental impacts, but can be challenging to observe in winter conditions. Here, we use multi-sensor satellite data to assess sulfur dioxide (SO2) emissions from the 2012–2013 eruption of Plosky Tolbachik volcano (Kamchatka), which lasted ~ 9–10 months and erupted ~ 0.55 km3 DRE. Observations from the Ozone Monitoring Instrument (OMI), the Ozone Mapping and Profiler Suite (OMPS), the Atmospheric Infrared Sounder (AIRS), and the Moderate Resolution Imaging Spectroradiometer (MODIS) are used to evaluate volcanic activity, SO2 emissions and heat flux associated with the effusion of lava flows. Gaps in the primary OMI SO2 time-series dataset occurred due to instrument limitations and adverse meteorological conditions. Four methods were tested to assess how efficiently they could fill these data gaps and improve estimates of total SO2 emissions. When available, using data from other {SO2} observing instruments was the most comprehensive way to address these data gaps. Satellite measurements yield a total SO2 loading of ~ 200 kt SO2 during the 10-month Plosky Tolbachik eruption, although actual SO2 emissions may have been greater. Based on the satellite SO2 measurements, the Fast Fourier Transform (FFT) multi-taper method (MTM) was used to analyze cyclical behavior in the complete data series and a 55-day cycle potentially attributable to the eruptive behavior of Plosky Tolbachik during the 2012 – 2013 eruption was identified.
Tibaldi Alessandro, Corazzato Claudia, Kozhurin Andrey, Lagmay Alfredo F.M., Pasquarè Federico A., Ponomareva Vera V., Rust Derek, Tormey Daniel, Vezzoli Luigina Influence of substrate tectonic heritage on the evolution of composite volcanoes: Predicting sites of flank eruption, lateral collapse, and erosion // Global and Planetary Change. 2008. V. 61. № 3-4. P. 151-174. doi:10.1016/j.gloplacha.2007.08.014.    Аннотация
This paper aims to aid understanding of the complicated interplay between construction and destruction of volcanoes, with an emphasis on the role of substrate tectonic heritage in controlling magma conduit geometry, lateral collapse, landslides, and preferential erosion pathways. The influence of basement structure on the development of six composite volcanoes located in different geodynamic/geological environments is described: Stromboli (Italy), in an island arc extensional tectonic setting, Ollagüe (Bolivia–Chile) in a cordilleran extensional setting, Kizimen (Russia) in a transtensional setting, Pinatubo (Philippines) in a transcurrent setting, Planchon (Chile) in a compressional cordilleran setting, and Mt. Etna (Italy) in a complex tectonic boundary setting. Analogue and numerical modelling results are used to enhance understanding of processes exemplified by these volcanic centres. We provide a comprehensive overview of this topic by considering a great deal of relevant, recently published studies and combine these with the presentation of new results, in order to contribute to the discussion on substrate tectonics and its control on volcano evolution. The results show that magma conduits in volcanic rift zones can be geometrically controlled by the regional tectonic stress field. Rift zones produce a lateral magma push that controls the direction of lateral collapse and can also trigger collapse. Once lateral collapse occurs, the resulting debuttressing produces a reorganization of the shallow-level magma migration pathways towards the collapse depression. Subsequent landslides and erosion tend to localize along rift zones. If a zone of weakness underlies a volcano, long-term creep can occur, deforming a large sector of the cone. This deformation can trigger landslides that propagate along the destabilized flank axis. In the absence of a rift zone, normal and transcurrent faults propagating from the substrate through the volcano can induce flank instability in directions respectively perpendicular and oblique to fault strike. This destabilization can evolve to lateral collapse with triggering mechanisms such as seismic activity or magmatic intrusion.
Tolstykh M.L., Naumov V.B., Gavrilenko M.G., Ozerov A.Yu., Kononkova N.N. Chemical composition, volatile components, and trace elements in the melts of the Gorely volcanic center, southern Kamchatka: Evidence from inclusions in minerals // Geochemistry International. 2012. V. 50. № 6. P. 522-550. doi:10.1134/S0016702912060079.
Torsvik T., Paris R., Didenkulova I., Pelinovsky E., Belousov A., Belousova M. Numerical simulation of a tsunami event during the 1996 volcanic eruption in Karymskoye lake, Kamchatka, Russia // Natural Hazards and Earth System Science. 2010. V. 10. № 11. P. 2359-2369. doi:10.5194/nhess-10-2359-2010.





 

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