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Carter A.J., Girina O.A., Ramsey M.S., Demyanchuk Yu.V. ASTER and field observations of the 24 December 2006 eruption of Bezymianny Volcano, Russia // Remote Sensing of Environment. 2008. V. 112. P. 2569-2577.    Аннотация
An explosive eruption occurred at Bezymianny Volcano (Kamchatka Peninsula, Russia) on 24 December 2006 at 09:17 (UTC). Seismicity
increased three weeks prior to the large eruption, which produced a 12–15 km above sea level (ASL) ash column. We present field observations from 27 December 2006 and 2 March 2007, combined with satellite data collected from 8 October 2006 to 11 April 2007 by the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER), as part of the instrument's rapid-response program to volcanic eruptions. Pixel-integrated brightness temperatures were calculated from both ASTER 90 m/pixel thermal infrared (TIR) data as well as 30 m/pixel shortwave infrared (SWIR) data. Four days prior to the eruption, the maximum TIR temperature was 45 °C above the average background temperature (−33 °C) at the dome, which we interpret was a precursory signal, and had dropped to 8 °C above background by 18 March 2007. On 20 December 2006, there was also a clear thermal signal in the SWIR data of 128 °C using ASTER Band 7 (2.26 μm). The maximum SWIR temperature was 181 °C on the lava dome on 4 January 2007, decreasing below the detection limit of the SWIR data by 11 April 2007. On 4 January 2007 a hot linear feature was observed at the dome in the SWIR data, which produced a maximum temperature of 700 °C for the hot fraction of the pixel using the dual band technique. This suggests that magmatic temperatures were present at the dome at this time, consistent with the emplacement of a new lava lobe following the eruption. The eruption also produced a large, 6.5 km long by up to 425 m wide pyroclastic flow (PF) deposit that was channelled into a valley to the south–southeast. The PF deposit cooled over the following three months but remained elevated above the average background temperature. A second field investigation in March 2007 revealed a still-warm PF deposit that contained fumaroles. It was also observed that the upper dome morphology had changed in the past year, with a new lava lobe having in-filled the crater that formed following the 9 May 2006 eruption. These data provide further information on effusive and explosive activity at Bezymianny using quantitative remote sensing data and reinforced by field observations to assist in pre-eruption detection as well as post-eruption monitoring.
Carter Adam J., Ramsey Michael S., Belousov Alexander B. Detection of a new summit crater on Bezymianny Volcano lava dome: satellite and field-based thermal data // Bulletin of Volcanology. 2007. V. 69. № 7. P. 811-815. doi:10.1007/s00445-007-0113-x.
Caudron Corentin, Taisne Benoit, Kugaenko Yulia, Saltykov Vadim Magma migration at the onset of the 2012–13 Tolbachik eruption revealed by Seismic Amplitude Ratio Analysis // Journal of Volcanology and Geothermal Research. 2015. V. 307. P. 60 - 67. doi: 10.1016/j.jvolgeores.2015.09.010.    Аннотация
Abstract In contrast of the 1975–76 Tolbachik eruption, the 2012–13 Tolbachik eruption was not preceded by any striking change in seismic activity. By processing the Klyuchevskoy volcano group seismic data with the Seismic Amplitude Ratio Analysis (SARA) method, we gain insights into the dynamics of magma movement prior to this important eruption. A clear seismic migration within the seismic swarm, started 20 hours before the reported eruption onset (05:15 UTC, 26 November 2012). This migration proceeded in different phases and ended when eruptive tremor, corresponding to lava flows, was recorded (at ~ 11:00 UTC, 27 November 2012). In order to get a first order approximation of the magma location, we compare the calculated seismic intensity ratios with the theoretical ones. As expected, the observations suggest that the seismicity migrated toward the eruption location. However, we explain the pre-eruptive observed ratios by a vertical migration under the northern slope of Plosky Tolbachik volcano followed by a lateral migration toward the eruptive vents. Another migration is also captured by this technique and coincides with a seismic swarm that started 16–20 km to the south of Plosky Tolbachik at 20:31 {UTC} on November 28 and lasted for more than 2 days. This seismic swarm is very similar to the seismicity preceding the 1975–76 Tolbachik eruption and can be considered as a possible aborted eruption.
Chaplygin Ilya, Yudovskaya Marina, Vergasova Lidiya, Mokhov Andrey Native gold from volcanic gases at Tolbachik 1975–76 and 2012–13 Fissure Eruptions, Kamchatka // Journal of Volcanology and Geothermal Research. 2015. V. 307. P. 200 - 209. doi: 10.1016/j.jvolgeores.2015.08.018.    Аннотация
Abstract Aggregates and euhedral crystals of native gold were found in sublimates formed during New Tolbachik Fissure Eruption in 2012–2013 (NTFE). Gold-bearing sublimate samples were taken from a red-hot (690 °C) degassing fracture in the roof of an active lava tunnel 1.5 km from active Naboko cinder cone in May 2013. The gas condensate collected at 690 °C in this site contains 16 ppb Au, 190 ppb Ag and 1180 ppm Cu compared to 3 ppb Au, 39 ppb Ag and 9.7 ppm Cu in the condensate of pristine magmatic gas sampled at 1030 °C. The 690 °C volcanic gas is most likely a mix of magmatic gas and local snow buried under the lava flows as indicated by oxygen and hydrogen isotope compositions of the condensate. The lower-temperature gas enrichment in gold, copper and chlorine is resulted from evaporation of the 690 °C condensate during forced gas pumping at sampling. Native gold was also found in fumarolic encrustations collected from caverns in basalt lava flows with temperature up to 600 °C in June 2014, in a year after eruption finished. The native gold precipitation in newly formed Cu-rich sublimates together with the well known gold occurrences in cinder cones of 1975–1976 Large Tolbachik Fissure Eruption manifest a transport capability of oxidized volcanic gas.
Churikova T., Gordeychik B., Iwamori H., Nakamura H., Ishizuka O., Nishizawa T., Haraguchi S., Yasukawa K., Miyazaki T., Vaglarov B., Ueki K., Toyama C., Chang Q., Kimura J.I. Geology, petrology and geochemistry of the Tolbachik volcanic massif, Kamchatka, Russia // 26th IUGG General Assembly 2015. June 22 - July 2, 2015, Prague, Czech Republic. Prague, Czech Republic: IUGG. 2015. P. VS28p-487.    Аннотация
Data on the geology, petrography, and geochemistry of previously geochemically unstudied Middle-Late-Pleistocene rocks from Tolbachik volcanic massif (Central Kamchatka Depression, CKD) are presented. Two volcanic series – middle-K and high-K were erupted. The geochemical history of the massif was started earlier 86 ka (K-Ar dating) with the formation of the Tolbachik pedestal presented by middle-K series. During stratovolcanoes formation both series occur and the role of high-K melts was increasing with time. In Holocene high-K rocks are dominated but some cinder cone lavas are presented by middle-K high-Mg melts which suggest that both volcanic series are still exists. The computer modeling show that both series can be explained by the process of crystal fractionation at different water content from nearly or the same mantle source similar to high-Mg basalts of 1975 Northern Breakthrough. Middle-K rocks could crystallize at water-rich conditions (more than 2% of H2O) while the high-K rock could crystallize at dry conditions at the same pressure. However the existence of different mantle sources and possible magma mixing cannot be excluded. Our data show that fractional crystallization at different P-T-H2O-fO2 conditions can be one of the main processes responsible for rock variations at CKD. Sr-Nd-Pb isotopes suggest 2-4% of crustal assimilation to the magma chamber during pedestal and stratovolcanoes formation while lava-cinder cones are not show evidences of crustal assimilation. Major and trace element data coupled with K-Ar dating provide strong evidence that Povorotnaya mount located in 8 km NE of Plosky Tolbachik is the old block of the Tolbachik massif pedestal and for the moment the oldest known object (306 ka by K-Ar dating) in Klyuchevskaya group.

Geology, petrology and geochemistry of the Tolbachik volcanic massif, Kamchatka, Russia. Available from: https://www.researchgate.net/publication/282656425_Geology_petrology_and_geochemistry_of_the_Tolbachik_volcanic_massif_Kamchatka_Russia [accessed Jun 19, 2017].
Churikova T., Gordeychik B., Wörner G., Ivanov B., Maximov A. Mineralogy and petrology of Kamen volcano rocks, Kamchatka // Mitigating natural hazards in active arc environments. Linkages among tectonism, earthquakes, magma genesis and eruption in volcanic arcs, with a special focus on hazards posed by arc volcanism and great earthquakes. June 22-26, 2009, Fairbanks, Alaska. Fairbanks, Alaska: Geophysical Institute, University of Alaska. 2009. P. 117-118.
Churikova T., Gordeychik B., Wörner G. Mantle and fluid sources below Klyuchevskoy-Kamen-Bezymianny line (Kamchatka) // Geofluid-3. Nature and Dynamics of fluids in Subduction Zones. Tokyo, Japan, February 28 - March 3, 2014. Tokyo, Japan: Tokyo Institute of Technology. 2014. P. 72    Аннотация
Kamen volcano is an extinct volcanic complex located in the central part of the Klyuchevskaya group of volcanoes (KGV) between active Klyuchevskoy, Bezymianny, and Ploskie Sopky volcanoes. Kamen volcano was mapped by V.A. Ermakov only in the 1970s. However the modern geochemical studies of Kamen volcano have not been previously carried out and its relationship and petrogenesis in comparison to other active neighbors are unknown. A modern geochemical study of Kamen volcano is needed because it will shed light not only on the history of the volcano itself and its closest neighbors, but also on the history and magmatic evolution of the KGV melts in general. The distance between the summits of Kamen and Klyuchevskoy is only 5 km, the same as between Kamen and Bezymianny. The close relationship in space and time of the KGV and the common zone of seismicity below them suggests a common source and a possible genetic relationship between their magmas. However, the Late-Pleistocene-Holocene lavas of all these neighboring volcanoes are very different: high-Mg and high-Al Ol-Cpx-Pl basalts and basaltic andesites occur at Klyuchevskoy volcano, and Hbl-bearing andesites and dаcites dominate at Bezymianny volcano. The rocks of Ploskie Sopky volcano, situated only 10 km NW of Kamen, are represented by medium-high-K subalkaline lavas.
https://www.researchgate.net/publication/283481841 [связанный ресурс]
Churikova T.G., Gordeychik B.N., Edwards B.R., Ponomareva V.V., Zelenin E.A. The Tolbachik volcanic massif: A review of the petrology, volcanology and eruption history prior to the 2012–2013 eruption // Journal of Volcanology and Geothermal Research. 2015. V. 307. P. 3 - 21. doi: 10.1016/j.jvolgeores.2015.10.016.    Аннотация
The primary goal of this paper is to summarize all of the published data on the Tolbachik volcanic massif in order to provide a clear framework for the geochronologic, petrologic, geochemical and to a lesser extent the geophysical and tectonic characteristics of the Tolbachik system established prior to the 2012–2013 eruption. The Tolbachik massif forms the southwestern part of the voluminous Klyuchevskoy volcanic group in Kamchatka. The massif includes two large stratovolcanoes, Ostry (“Sharp”) Tolbachik and Plosky (“Flat”) Tolbachik, and a 70 km long zone of the basaltic monogenetic cones that form an arcuate rift-like structure running across the Plosky Tolbachik summit. The Tolbachik massif gained international attention after the 1975–1976 Great Tolbachik Fissure Eruption (GTFE), which was one of the largest eruptions of the 20th century and one of the six largest basaltic fissure eruptions in historical time. By the end of the GTFE, 2.2 km3 of volcanic products of variable basaltic compositions with MORB-like isotopic characteristics covered an area of > 1000 km2. During the following three decades more than 700 papers on various aspects of this eruption have been published both in national and international journals. Although the recent 2012–2013 eruption, which is the main topic of this volume, was not as long as the {GTFE} in duration or as large in area and volume of the erupted deposits, it brought to the surface a unique volcanic material never found before. In order to understand the data from new eruptions and make significant progress towards a better understanding of the Tolbachik magmatic system it is important to be able to put the new results into the historic context of previous research.
Churikova T.G., Gordeychik B.N., Fedotov S.A. National report for the International Association of Volcanology and Chemistry of the Earth’s Interior of the International Union of Geodesy and Geophysics 2011–2014. Presented to the XXVI General Assembly of the IUGG // Geoinformatics Research Papers. Proceedings of the Geophysical center RAS. 2015. V. 3. V. BS3011. P. 1-185. doi: 10.2205/2015IUGG-RU-IAVCEI.    Аннотация
In the present National Report, major results are given of research conducted by Russian scientists in 2011–2014 on the topics of the International Association of Volcanology and Chemistry of the Earth’s Interior (IAVCEI) of the International Union of Geodesy and Geophysics. Kamchatka Peninsula with its famous Klyuchevskaya Group of volcanoes is the most volcanically active area in Russia and one of the most active in the world. Majority of researches and scientific results on Volcanology and Geochemistry of the Earth’s Interior during 2011–2014 were achieved in this region including recent data on new Tolbachik fissure eruption in 2012–2013. Besides it, the scientific results on the magmatism outside Russia, which were achieved by Russian scientists, are also included in this review. Major achievements in the chemistry of the Earth, geothermy, geodynamics, geochronology and deep mantle structure are featured. The studies as for the single volcanoes as well the regional observations are outlined. The theoretical and applied efforts connected to the volcanological processes are considered. The main conclusions are illustrated by summarized figures. All the required references are given.

В данном Национальном отчете представлены основные результаты исследований, проводимых российскими учеными в 2011—2014 гг., по темам, соответствующим направлениям деятельности Международной ассоциации вулканологии и химии недр Земли (МАВХНЗ) Международного геодезического и геофизического союза (МГГС). Полуостров Камчатка с его знаменитой Ключевской группой вулканов являются наиболее вулканически активной областью России и одной из самых активных в мире. Основные результаты исследований по вулканологии и химии недр Земли в 2011—2014 гг. были получены в данном регионе, включая недавние данные по новому трещинному извержению вулкана Толбачик в 2012—2013 гг. Кроме того, в отчет включены полученные российскими учеными научные результаты по магматизму за пределами России. В отчете представлены основные достижения по геохимии, геотермии, геодинамике, геохронологии и глубинному строению мантии. Описаны исследования как для отдельных вулканов, так и для целых регионов. Рассмотрены теоретические прикладные вопросы вулканических процессов. Основные выводы приведены на сводных иллюстрациях. Приведены все требуемые ссылки.
Churikova T.G., Ivanov B.V., Eichelberger J., Wörner G., Browne B., Izbekov P. Major and trace element zoning in plagioclase from Kizimen Volcano (Kamchatka): Insights into magma-chamber processes // Journal of Volcanology and Seismology. 2013. V. 7. № 2. P. 112-130. doi:10.1134/S0742046313020024.    Аннотация
The data on the geochemistry of the rocks of Kizimen Volcano and results of microprobe studies of major and trace elements in plagioclase grains from acid lavas and basalt inclusions are presented. The characteristics of the Kizimen Volcano are the following: (1) basalt inclusions are abundant in acid lavas; (2) banded, mixed lavas occur; (3) the distribution curves of rare earth elements of acidic lavas and basalt inclusions intersect; (4) Sr–Nd isotope systematics of the rocks and inclusions do not indicate mixture with crustal material; (5) plagioclase phenocrysts are of direct and reverse zonation; (6) olivine and hornblende, as well as acid and mafic plagioclases, coexist in the rocks. The studies revealed that the rocks are of a hybrid nature and originated in the course of repeated mixture of acid and mafic melts either with chemical and ther mal interaction of melts or exclusively thermal ones. Study of the major and trace element distribution in zonal minerals provides an informative tool for understanding the history of the generation and evolution of melts in a magma chamber
Churikova Tatiana G., Gordeychik Boris N., Ivanov Boris V., Wörner Gerhard Relationship between Kamen Volcano and the Klyuchevskaya group of volcanoes (Kamchatka) // Journal of Volcanology and Geothermal Research. 2013. V. 263. P. 3 - 21. doi: 10.1016/j.jvolgeores.2013.01.019.    Аннотация
Abstract Data on the geology, petrography, mineralogy, and geochemistry of rocks from Kamen Volcano (Central Kamchatka Depression) are presented and compared with rocks from the neighbouring active volcanoes. The rocks from Kamen and Ploskie Sopky volcanoes differ systematically in major elemental and mineral compositions and could not have been produced from the same primary melts. The compositional trends of Kamen stratovolcano lavas and dikes are clearly distinct from those of Klyuchevskoy lavas in all major and trace element diagrams as well as in mineral composition. However, lavas of the monogenetic cones on the southwestern slope of Kamen Volcano are similar to the moderately high-Mg basalts from Klyuchevskoy and may have been derived from the same primary melts. This means that the monogenetic cones of Kamen Volcano represent the feeding magma for Klyuchevskoy Volcano. Rocks from Kamen stratovolcano and Bezymianny form a common trend on all major element diagrams, indicating their genetic proximity. This suggests that Bezymianny Volcano inherited the feeding magma system of extinct Kamen Volcano. The observed geochemical diversity of rocks from the Klyuchevskaya group of volcanoes can be explained as the result of both gradual depletion over time of the mantle N-MORB-type source due to the intense previous magmatic events in this area, and the addition of distinct fluids to this mantle source.
Churikova Tatiana G., Gordeychik Boris N., Iwamori Hikaru, Nakamura Hitomi, Ishizuka Osamu, Nishizawa Tatsuji, Haraguchi Satoru, Miyazaki Takashi, Vaglarov Bogdan S. Petrological and geochemical evolution of the Tolbachik volcanic massif, Kamchatka, Russia // Journal of Volcanology and Geothermal Research. 2015. V. 307. P. 156 - 181. doi: 10.1016/j.jvolgeores.2015.10.026.    Аннотация
Data on the geology, petrography, and geochemistry of Middle–Late-Pleistocene rocks from the Tolbachik volcanic massif (Kamchatka, Klyuchevskaya group of volcanoes) are presented and compared with rocks from the neighboring Mount Povorotnaya, Klyuchevskaya group basement, and Holocene–historical Tolbachik monogenetic cones. Two volcanic series of lavas, middle-K and high-K, are found in the Tolbachik massif. The results of our data analysis and computer modeling of crystallization at different P–T–H2O–fO2 conditions allow us to reconstruct the geochemical history of the massif. The Tolbachik volcanic massif started to form earlier than 86 ka based on K–Ar dating. During the formation of the pedestal and the lower parts of the stratovolcanoes, the middle-K melts, depleted relative to NMORB, fractionated in water-rich conditions (about 3 of H2O). At the Late Pleistocene–Holocene boundary, a large fissure zone was initiated and the geodynamical regime changed. Upwelling associated with intra-arc rifting generated melting from the same mantle source that produced magmas more enriched in incompatible trace elements and subduction components; these magmas are high-K, not depleted relative to N-MORB melts with island arc signatures and rift-like characteristics. The fissure opening caused degassing during magma ascent, and the high-K melts fractionated at anhydrous conditions. These high-K rocks contributed to the formation of the upper parts of stratovolcanoes. At the beginning of Holocene, the high-K rocks became prevalent and formed cinder cones and associated lava fields along the fissure zone. However, some features, including 1975–1976 Northern Breakthrough, are represented by middle-K high-Mg rocks, suggesting that both middle-K and high-K melts still exist in the Tolbachik system. Our results show that fractional crystallization at different water conditions and a variably depleted upper mantle source are responsible for all observed variations in rocks within the Tolbachik volcanic massif. Sr–Nd isotopes are consistent with 2–4 crustal assimilation during formation of the pedestal and stratovolcanoes, while the young lava fields do not show evidence of crustal assimilation. Major and trace element data coupled with K–Ar dating provide strong evidence that Mount Povorotnaya, located in 8 km northeast of Plosky Tolbachik, is an old block of the Tolbachik massif pedestal and for the moment it is the oldest (306 ka) known object in Klyuchevskaya group of volcanoes.
Churikova Tatiana, Gordeychik Boris, Iwamori Hikaru, Nakamura Hitomi, Nishizawa Tatsuji, Haraguchi Satoru, Yasukawa Kazatuka, Ishizuka Osamu Petrology and geochemistry of the Tolbachik stratovolcano // 8th Biennial Workshop on Japan-Kamchatka-Alaska Subduction Processes. Finding clues for science and disaster mitigation from international collaboration (JKASP-2014). 22-26 September 2014, Sapporo, Japan. Sapporo, Japan: Hokkaido University. 2014. P. 1-3.    Аннотация
The numerous of national and international publications were dedicated to Plosky Tolbachik volcano eruptions and adjacent monogenetic cones, which were erupted repeatedly during Holocene, including historical time [i.e. Vlodavets, 1937; Popkov, 1946; Peep, 1946, 1954; Menyailov, 1953; Sirin and Farberov, 1963; Kirsanov et al., 1974; Ivanov and Khrenov, 1979; Fedotov, 1984; Krivenko, 1990; Kersting, 1995; Tatsumi et al., 1995; Hochstaedter et al., 1996; Kepezhinskas et al., 1997; Turner et al., 1998; Pineau et al., 1999; Volynets et al., 2000; Churikova et al., 2001; Münker et al., 2004; Portnyagin et al., 2007; Volynets et al., 2013]. However, all these data mainly relates to monogenetic cones, but the information on stratovolcanoes itself practically absent. There are only few papers on Ostry and Plosky Tolbachik stratovolcanoes focusing on geology [Ermakov and Vazheevskaya, 1973], petrography and some petrochemistry of the rocks [Ermakov, 1977; Flerov and Melekestsev, 2013]. The modern geochemical and isotope studies of the stratovolcanoes were never achieved. In this report we present geological, petrographical, petrochemical, geochemical and some K-Ar data on the rocks of Tolbachik massif. The present report based on representative collection of 154 samples from stratovolcanoes, dikes, monogenetic cones of different ages, including last 2012-2013 eruption. Additionally our study included samples separately standing edifice of Povorotnaya mount, which age according to K-Ar dating is 0.306±0.01 Ма.
Churikova Tatiana, Gordeychik Boris, Wörner Gerhard, Flerov Gleb, Hartmann Gerald, Simon Klaus Geochemical evolution of Bolshaya Udina, Malaya Udina, and Gorny Zub volcanoes, Klyuchevskaya Group (Kamchatka) // Geophysical Research Abstracts. 2017. V. 19. P. EGU2017-10691.    Аннотация
The Klyuchevskaya group of volcanoes (KGV) located in the northern part of Kamchatka has the highest magma production rate for any arc worldwide and several of its volcanoes have been studied in considerable detail [e.g. Kersting & Arculus, 1995; Pineau et al., 1999; Dorendorf et al., 2000; Ozerov, 2000; Churikova et al., 2001, 2012, 2015; Mironov et al., 2001; Portnyagin et al., 2007, 2015; Turner et al., 2007]. However, some volcanoes of the KGV including Late-Pleistocene volcanoes Bolshaya Udina, Malaya Udina, Ostraya Zimina, Ovalnaya Zimina, and Gorny Zub were studied only on a reconnaissance basis [Timerbaeva, 1967; Ermakov, 1977] and the modern geochemical studies have not been carried out at all. Among the volcanoes of KGV these volcanoes are closest to the arc trench and may hold information on geochemical zonation with respect to across arc source variations. We present the first major and trace element data on rocks from these volcanoes as well as on their basement. All rocks are medium-calc-alkaline basaltic andesites to dacites except few low-Mg basalts from Malaya Udina volcano. Phenocrysts are mainly olivine, pyroxene, plagioclase and magnetite, Hb-bearing andesites and dacites are rarely found only in subvolcanic intrusions at Bolshaya Udina volcano. Lavas are geochemically similar to the active Bezymianny volcano, however, individual variations for each volcano exist in both major and trace elements. Trace element geochemistry is typical of island arc volcanism. Compared to KGV lavas all studied rocks form very narrow trends in all major element diagrams, which almost do not overlap with the fields of other KGV volcanoes. The lavas are relatively poor in alkalis, TiO2, P2O5, FeO, Ni, Zr, and enriched in SiO2 compared to other KGV volcanics and show greater geochemical and petrological evidence of magmatic differentiation during shallow crustal processing. Basement samples of the Udinskoe plateau lavas to the east of Bolshaya Udina volcano have similar geochemical composition (trace element enriched high-K basaltic andesites and andesites) and similar eruption age of 274 ka [Calkins et al., 2004] as typical plateau lavas below the northern KGV. This research was supported by RFBR-DFG grant # 16-55-12040.
Churikova Tatiana, Wörner Gerhard, Mironov Nikita, Kronz Andreas Volatile (S, Cl and F) and fluid mobile trace element compositions in melt inclusions: implications for variable fluid sources across the Kamchatka arc // Contributions to Mineralogy and Petrology. 2007. V. 154. № 2. P. 217-239. doi:10.1007/s00410-007-0190-z.    Аннотация
Volatile element, major and trace element compositions were measured in glass inclusions in olivine from samples across the Kamchatka arc. Glasses were analyzed in reheated melt inclusions by electron microprobe for major elements, S and Cl, trace elements and F were determined by SIMS. Volatile element–trace element ratios correlated with fluid-mobile elements (B, Li) suggesting successive changes and three distinct fluid compositions with increasing slab depth. The Eastern Volcanic arc Front (EVF) was dominated by fluid highly enriched in B, Cl and chalcophile elements and also LILE (U, Th, Ba, Pb), F, S and LREE (La, Ce). This arc-front fluid contributed less to magmas from the central volcanic zone and was not involved in back arc magmatism. The Central Kamchatka Depression (CKD) was dominated by a second fluid enriched in S and U, showing the highest S/K2O and U/Th ratios. Additionally this fluid was unusually enriched in 87Sr and 18O. In the back arc Sredinny Ridge (SR) a third fluid was observed, highly enriched in F, Li, and Be as well as LILE and LREE. We argue from the decoupling of B and Li that dehydration of different water-rich minerals at different depths explains the presence of different fluids across the Kamchatka arc. In the arc front, fluids were derived from amphibole and serpentine dehydration and probably were water-rich, low in silica and high in B, LILE, sulfur and chlorine. Large amounts of water produced high degrees of melting below the EVF and CKD. Fluids below the CKD were released at a depth between 100 and 200 km due to dehydration of lawsonite and phengite and probably were poorer in water and richer in silica. Fluids released at high pressure conditions below the back arc (SR) probably were much denser and dissolved significant amounts of silicate minerals, and potentially carried high amounts of LILE and HFSE.
Clarke Amanda B., Ongaro Tomaso, Belousov Alexander Vulcanian Eruptions // Encyclopedia of Volcanoes. Academic Press: Elsevier. 2015. P. 505-518.





 

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