First data on major, minor and trace element (XRF. ICP-MS) concentrations in the volcanic rocks of the IVS 50th anniversary Fissure Tolbachik eruption are reported for the period from 27.11.2012 to 25.01.2013; scheme of lava flows distribution by March 2013 is made. The volcanic rocks of the new eruption are substantially different from the other studied volcanic rocks of Tolbachinsky Dol by their higher alkalis and incompatible elements content. The rocks of the first three days of eruption (Menyailov Vent) have higher silica and alkalis content than all previously reported volcanic rocks of Tolbachinsky Dol. Volcanic rocks of the Naboko Vent, at silica content similar to high-Al basalts of Tolbachinsky Dol, have different concentrations of trace elements and some major elements (K2O, CaO, TiO2, P2O5). REE and other incompatible element concentrations in the rocks of the Menyailov Vent are higher than in the rocks of the Naboko Vent at the same element ratios. The differences of the volcanic rocks of the two vents of the new eruption may be caused by the fact that the erupted lavas came from the different levels of the same magma chamber.

Abstract Here we present the results from monitoring of the composition of rocks produced during the 2012–2013 fissure eruption at Tolbachik volcano (FTE). Major and trace element concentrations in 75 samples are reported. Products of this eruption are represented by high alumina basaltic trachyandesites with higher alkalis and titanium contents than in all previously studied rocks of the Tolbachik monogenetic volcanic field. Rocks erupted during the first three days (27–30 November) from the northern (also called Menyailov) group of vents are the most silica- and alkali-rich (SiO2 concentrations up to 55.35 wt. and {K2O} up to 2.67 wt.). From December onwards, when the eruptive activity switched from the Menyailov vents to the southern (Naboko) group of vents, silica content dropped by 2 wt., concentrations of MgO, FeO, TiO2 and Mg# increased, and {K2O} and Na2O concentrations and K2O/MgO ratio decreased. For the rest of the eruption the compositions of rocks remained constant and homogeneous; no systematic compositional differences between lava, bombs and scoria samples are evident. Trace element distributions in the rocks of the Menyailov and Naboko vent lavas are relatively uniform; Menyailov lavas have slightly higher Th, Nb, Hf, Y, and {HREE} concentrations than the Naboko vent lavas at more or less constant element ratios. We explain the initial change in geochemistry by tapping of a slightly cooler and fractionated (~ 3 Mt and 8 Cpx) upper part of the magma storage zone before the main storage area began to feed the eruption. Thermodynamic constraints show that apparent liquidus temperatures varied from 1142 °C to 1151 °C, and thermodynamic modeling shows that variations in compositions are consistent with a high degree of low pressure (100–300 MPa), nominally anhydrous fractionation of a parent melt compositionally similar to the 1975 Northern Breakthrough high-Mg basalt. Geochemistry, petrological observations and modeling are in agreement with the newly erupted material being derived from remnant high-Al magma from the 1975–76 Southern Breakthrough eruption with only slight amounts of cooling (less than 1 °C per year) during the intervening 36 years.

We report, here, the composition and Ksingle bondAr ages of a representative collection of volcanic rocks that erupted within three monogenetic volcanic fields in the active fault zone of the Sredinny Range of Kamchatka: Tigilsky Dol, Mount Oxi massif and Anaunsky Dol. The studied rocks display a wide range of compositions (medium-K, moderate-Mg, high-K, high-Ti and high-Mg basalts, and high-LREE picrobasalts); the high-Mg varieties are confined to faults. Five main periods of volcanic activity were investigated, 4.3–3, 2, 1.5, 1 Ma and from 0.3 to <0.05 Ma. Primitive lavas first emerged on the surface at 3.5 Ma. There was a massive outpouring of high-Mg lavas at 1.5–1 and 0.3 Ma, which could have been related to the formation of the fault zone. This is the first report of rocks in Kamchatka with a high-LREE picrobasaltic composition (1.5 Ma). The Fo content of the olivine phenocrysts reaches 93.2 mol%, which is the highest value known for Quaternary Kamchatka basalts. A very heterogeneous source, even for individual eruptions is indicated by the minor element contents in the olivine (Ni, Mn and Ca); Cr-spinel – olivine paragenesis show that all the rocks studied crystallized in the same temperature range (1111–1292 °C), whereas the oxygen fugacity for the different samples varied from ΔQFM +0.7 to +2.0 log. units. A melt inclusion study showed that the Mg basalts of the Mt. Oxi massif and the high-LREE picrobasalts of Tigilsky Dol had different fluid sources that were enriched and depleted in water and Cl, respectively. We argue that the fluid source for the Mt. Oxi massif was likely the remains of the Pacific slab under the Sredinny Range, whereas, for the high-LREE picrobasalts of Tigilsky Dol, it was the lithospheric lithologies. The low content of S and high content of Cu in the oxidized high-LREE basalts provide additional evidence that they originated from the re-melting of sulfur-poor lithospheric lithologies. Both the fault zone and the lithosphere re-activation in the region are likely linked to the regional stress field.

This paper presents the results of studying the spatial distribution and structural setting of magnesian basalts and andesites in the Northern group of Kamchatkan volcanoes and in the junction zone of the Kuril-Kamchatka and Aleutian island arcs. The morphology and geologic structure of unique Kamchatkan magnesian basalt stratovolcanoes are described: Kharchinsky, Zarechnyi, and the Kharchinsky regional zone of cinder cones. The reported evidence includes the ages and eruptive histories, and productivities of the volcanoes and the volumes and weights of their edifices. The magnesian basalts were erupted 40-50 thousand years ago, for the first time during the Holocene.

Most of the Kharchinskii and Zarechnyi products, as well as those of the Kharchinskii cinder cones, are magnesian rocks. Mineralogical data suggest that both the basaltic and the andesitic magma were rich in water (≥3-4 and >6-7 wt., respectively) and crystallized at high oxygen fugacity (2.0-2.5 orders of magnitude higher than the NNO buffer). These features, coupled with the geochemical characteristics of these basalts and andesites, indicate that they are similar to the rocks of Shiveluch, a volcano also located on the northern flank of the Northern volcanic group, but differ from the rocks of the other volcanoes of this group which are located further south. The Kharchinskii, Zarechnyi, and Shiveluch magnesian basalts differ from the rocks of the Klyuchevskoi volcano and Tolbachik lava field by their higher K, Ba, Sr and lower Ca, Sc, Yb contents at higher La/Yb, Ni/Sc, and La/Ta ratios, while their initial magmas were more hydrous and more oxidized.

The eruptive history of the Shiveluch andesite volcano included two Holocene events, during which
the volcano erupted unusual rocks: medium-potassium, amphibole-bearing magnesian basalts (7600 years ago)
and high-potassium magnesian basalts with phlogopite and amphibole (3600 years ago). The volumes of tephra
were approximately 0.1 and 0.3 km3, respectively. Some of the mineralogical and geochemical features of the
Holocene basalts were inherited by the subsequent basaltic andesites and andesites. These are similar in Mg
variation ranges of olivine, clinopyroxene, and amphibole phenocrysts, high Mg contents, and high Cr and Ni
concentrations. This and the results of mass-balance calculations do not contradict the view that the Shiveluch
volcanic rocks originated during the crystal fractionation of Holocene basalt melts. However, the other
geochemical features of the Shiveluch rocks, e.g., their similar REE contents, cast doubt on the formation of
the magnesian basaltic andesites through fractional crystallization of magnesian basalt magma and suggest that
they originated as a result of interaction between magnesian basalt magma and a depleted mantle material at a
shallow depth. At the same time, the different mineral compositions of the Holocene medium- and high-potassium
basalts and the results of mass-balance calculations indicate that their parental magmas might be produced
by the melting of different rocks.