Abstract We report petrography, and bulk rock, mineral and glass analyses of eruptive products of the 2012–13 eruption of Tolbachik volcano, Central Kamchatka Depression, Russia. Magmas are shoshonitic in composition, with phenocrysts of olivine and plagioclase; clinopyroxene phenocrysts are scarce. Samples collected as bombs from the active vent, from liquid lava at the active lava front, and as naturally solidified “toothpaste” lava allow us to quantify changes in porosity and crystallinity that took place during 5.25 km of lava flow and during solidification. Olivine-hosted melt inclusions from rapidly-cooled, mm-size tephra have near-constant {H2O} contents (1.19 ± 0.1 wt) over a wide range of {CO2} contents (< 900 ppm), consistent with degassing. The groundmass glasses from tephras lie at the shallow end of this degassing trend with 0.3 wt {H2O} and 50 ppm CO2. The presence of small saturation, rather than shrinkage, bubbles testifies to volatile saturation at the time of entrapment. Calculated saturation pressures are 0.3 to 1.7 kbar, in agreement with the depths of earthquake swarms during November 2012 (0.6 to 7.5 km below the volcano). Melt inclusions from slowly-cooled and hot-collected lavas have {H2O} contents that are lower by an order of magnitude than tephras, despite comparable {CO2} contents. We ascribe this to diffusive {H2O} loss through olivine host crystals during cooling. The absence of shrinkage bubbles in the inclusions accounts for the lack of reduction in dissolved {CO2} (and S and Cl). Melt inclusions from tephras experienced < 3 wt post-entrapment crystallisation. Melt inclusion entrapment temperatures are around 1080 °C. Compared to magmas erupted elsewhere in the Kluchevskoy Group, the 2012–13 Tolbachik magmas appear to derive from an unusually H2O-poor and K2O-rich basaltic parent.

The 7600 14C-year-old Kurile Lake caldera-forming eruption (KO) in southern Kamchatka, Russia, produced a 7-km-wide caldera now mostly filled by the Kurile Lake. The KO eruption has a conservatively estimated tephra volume of 140–170 km3 making it the largest Holocene eruption in the Kurile–Kamchatka volcanic arc and ranking it among the Earth’s largest Holocene explosive eruptions. The eruptive sequence consists of three main units: (I) initial phreatoplinian deposits; (II) plinian fall deposits, and (III) a voluminous and extensive ignimbrite sheet and accompanying surge beds and co-ignimbrite fallout. The KO fall tephra was dispersed over an area of >3 million km2, mostly in a northwest direction. It is a valuable stratigraphic marker for southern Kamchatka, the Sea of Okhotsk, and a large part of the Asia mainland, where it has been identified as a f6 to 0.1 cm thick layer in terrestrial and lake sediments, 1000–1700 km from source. The ignimbrite, which constitutes a significant volume of the KO deposits, extends to the Sea of Okhotsk and the Pacific Ocean on either side of the peninsula, a distance of over 50 km from source. Fine co-ignimbrite ash was likely formed when the ignimbrite entered the sea and could account for the wide dispersal of the KO fall unit. Individual pumice clasts from the fall and surge deposits range from dacite to rhyolite, whereas pumice and scoria clasts in the ignimbrite range from basaltic andesite to rhyolite. Ignimbrite exposed west and south of the caldera is dominantly rhyolite, whereas north, east and southeast of the caldera it has a strong vertical compositional zonation from rhyolite at the base to basaltic andesite in the middle, and back to rhyolite at the top. Following the KO eruption, Iliinsky volcano formed within the northeastern part of the caldera producing basalt to dacite lavas and pyroclastic rocks compositionally related to the KO erupted products. Other post-caldera features include several extrusive domes, which form islands in Kurile Lake, submerged cinder cones and the huge silicic extrusive massif of Dikii Greben’ volcano.

Shiveluch Volcano, located in the Central Kamchatka Depression, has experienced multiple flank failures during its lifetime, most recently in 1964. The overlapping deposits of at least 13 large Holocene debris avalanches cover an area of approximately 200 km2 of the southern sector of the volcano. Deposits of two debris avalanches associated with flank extrusive domes are, in addition, located on its western slope. The maximum travel distance of individual Holocene avalanches exceeds 20 km, and their volumes reach ∼3 km3. The deposits of most avalanches typically have a hummocky surface, are poorly sorted and graded, and contain angular heterogeneous rock fragments of various sizes surrounded by coarse to fine matrix. The deposits differ in color, indicating different sources on the edifice. Tephrochronological and radiocarbon dating of the avalanches shows that the first large Holocene avalanches were emplaced approximately 4530–4350 BC. From ∼2490 BC at least 13 avalanches occurred after intervals of 30–900 years. Six large avalanches were emplaced between 120 and 970 AD, with recurrence intervals of 30–340 years. All the debris avalanches were followed by eruptions that produced various types of pyroclastic deposits. Features of some surge deposits suggest that they might have originated as a result of directed blasts triggered by rockslides. Most avalanche deposits are composed of fresh andesitic rocks of extrusive domes, so the avalanches might have resulted from the high magma supply rate and the repetitive formation of the domes. No trace of the 1854 summit failure mentioned in historical records has been found beyond 8 km from the crater; perhaps witnesses exaggerated or misinterpreted the events.

Volcanic eruptions from Kamchatka have deposited many unique tephra layers over a large region within the North Pacific, providing important isochrons between key sites such as marine ODP core 883 (Pacific Ocean, Detroit Seamount) and Elgygytgyn Lake (Chukotka, eastern Siberia). Here we present a compilation of C14 dates on major Holocene tephras from the volcanically highly active region, based on decades of detailed stratigraphical fieldwork on Shiveluch, Kliuchevskoy, and other volcanoes.The 12-m thick tephra sequence at the Kliuchevskoy slope has been continuously accumulating during the last ∼11 ka. It contains over 200 visible individual tephra layers and no datable organic material. The section is dominated by dark-gray mafic cinders related to Kliuchevskoy activity. In addition, it contains 30 light-colored thin layers of silicic tephra from distant volcanoes including 11 layers from Shiveluch volcano located only 65 km to the north. We have used EMPA glass analysis to correlate most of the marker tephra layers to their source eruptions dated earlier by C14 (Braitseva et al., 1997; Ponomareva et al., 2007), and in this way linked Kliuchevskoy tephra sequence to sequences at other volcanoes including Shiveluch. The C14 dates and tephras from the northern Kamchatka are then combined into a single Bayesian framework taking into account stratigraphical ordering within and between the sites. This approach has allowed us to enhance the reliability and precision of the estimated ages for the eruptions. Age-depth models are constructed to analyse changes in deposition rates and volcanic activity throughout the Holocene. This detailed chronology of the eruptions serves as a basis for understanding temporal patterns in the eruption sequence and geochemical variations of magmas. This research could prove important for the long-term forecast of eruptions and volcanic hazards.

On Kamchatka, detailed geologic and geomorphologic mapping of young volcanic terrains and observations on historical eruptions reveal that landslides of various scales, from small (0.001 km3) to catastrophic (up to 20–30 km3), are widespread. Moreover, these processes are among the most effective and most rapid geomorphic agents. Of 30 recently active Kamchatka volcanoes, at least 18 have experienced sector collapses, some of them repetitively. The largest sector collapses identified so far on Kamchatka volcanoes, with volumes of 20–30 km3 of resulting debris-avalanche deposits, occurred at Shiveluch and Avachinsky volcanoes in the Late Pleistocene. During the last 10,000 yr the most voluminous sector collapses have occurred on extinct Kamen' (4–6 km3) and active Kambalny (5–10 km3) volcanoes. The largest number of repetitive debris avalanches (> 10 during just the Holocene) has occurred at Shiveluch volcano. Landslides from the volcanoes cut by ring-faults of the large collapse calderas were ubiquitous. Large failures have happened on both mafic and silicic volcanoes, mostly related to volcanic activity. Orientation of collapse craters is controlled by local tectonic stress fields rather than regional fault systems.

Specific features of some debris avalanche deposits are toreva blocks — huge almost intact fragments of volcanic edifices involved in the failure; some have been erroneously mapped as individual volcanoes. One of the largest toreva blocks is Mt. Monastyr' — a ∼ 2 km3 piece of Avachinsky Somma involved in a major sector collapse 30–40 ka BP.

Long-term forecast of sector collapses on Kliuchevskoi, Koriaksky, Young Cone of Avachinsky and some other volcanoes highlights the importance of closer studies of their structure and stability.

Developing chronologies for sediments in the Arctic Ocean and its continental margins is an important but challenging task. Tephrochronology is a promising tool for independent age control for Arctic marine sediments and here we present the results of a cryptotephra study of a Holocene sedimentary record from the Chukchi Sea. Volcanic glass shards were identified and quantified in sediment core HLY0501-01 and geochemically characterized with single-shard electron microprobe and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). This enabled us to reveal a continuous presence of glass shards with identifiable chemical compositions throughout the core. The major input of glasses into the sediments is geochemically fingerprinted to the ∼3.6 ka Aniakchak caldera II eruption (Alaska), which provides an important chronostratigraphic constraint for Holocene marine deposits in the Chukchi-Alaskan region and, potentially, farther away in the western Arctic Ocean. New findings of the Aniakchak II tephra permit a reevaluation of the eruption size and highlight the importance of this tephra as a hemispheric late Holocene marker. Other identified glasses likely originate from the late Pleistocene Dawson and Old Crow tephras while some cannot be correlated to certain eruptions. These are present in most of the analyzed samples, and form a continuous low-concentration background throughout the investigated record. A large proportion of these glasses are likely to have been reworked and brought to the depositional site by currents or other transportation agents, such as sea ice. Overall, our results demonstrate the potential for tephrochronology for improving and developing chronologies for Arctic Ocean marine records, however, at some sites reworking and redistribution of tephra may have a strong impact on the record of primary tephra deposition.

This review is intended to highlight recent exciting advances in the study of distal (>100 km from the source) tephra and cryptotephra deposits and their potential application for volcanology. Geochemical correlations of tephra between proximal and distal locations have extended the geographical distribution of tephra over tens of millions square kilometers. Such correlations embark on the potential to reappraise volume and magnitude estimates of known eruptions. Cryptotephra investigations in marine, lake, and ice-core records also give rise to continuous chronicles of large explosive eruptions many of which were hitherto unknown. Tephra preservation within distal ice sheets and varved lake sediments permit precise dating of parent eruptions and provide new insight into the frequency of eruptions. Recent advances in analytical methods permit an examination of magmatic processes and the evolution of the whole volcanic belts at distances of hundreds and thousands of kilometers from source. Distal tephrochronology has much to offer volcanology and has the potential to significantly contribute to our understanding of sizes, recurrence intervals and geochemical make-up of the large explosive eruptions.

Very few age controls exist for Quaternary deposits over the vast territory of the East Russian Arctic, which hampers dating of major environmental changes in this area and prevents their correlation to climatic changes in the Arctic and Pacific marine domains. We report a newly identified ~177 ka old Rauchua tephra, which has been dispersed over an area of >1,500,000 km2 and directly links terrestrial paleoenvironmental archives from Arctic Siberia with marine cores in the northwest Pacific, thus permitting their synchronization and dating. The Rauchua tephra can help to identify deposits formed in terrestrial and marine environments during the oxygen isotope stage 6.5 warming event. Chemical composition of volcanic glass from the Rauchua tephra points to its island-arc origin, while its spatial distribution singles out the Kamchatka volcanic arc as a source. The Rauchua tephra represents a previously unknown, large (magnitude >6.5) explosive eruption from the Kamchatka volcanic arc.

We report tephrochronological and geochemical data on early Holocene activity from Plosky volcanic massif in the Kliuchevskoi volcanic group, Kamchatka Peninsula. Explosive activity of this volcano lasted for ~1.5 kyr, produced a series of widely dispersed tephra layers, and was followed by profuse low-viscosity lava flows. This eruptive episode started a major reorganization of the volcanic structures in the western part of the Kliuchevskoi volcanic group. An explosive eruption from Plosky (M~6), previously unstudied, produced tephra (coded PL2) of a volume of 10–12 km3 (11–13 Gt), being one of the largest Holocene explosive eruptions in Kamchatka. Characteristic diagnostic features of the PL2 tephra are predominantly vitric sponge-shaped fragments with rare phenocrysts and microlites of plagioclase, olivine and pyroxenes, medium- to high-K basaltic andesitic bulk composition, high-K, high-Al and high-P trachyandesitic glass composition with SiO2 = 57.5–59.5 wt%, K2O = 2.3–2.7 wt%, Al2O3 = 15.8–16.5 wt%, and P2O5 = 0.5–0.7 wt%. Other diagnostic features include a typical subduction-related pattern of incompatible elements, high concentrations of all REE (>10× mantle values), moderate enrichment in LREE (La/Yb ~ 5.3), and non-fractionated mantle-like pattern of LILE. Geochemical fingerprinting of the PL2 tephra with the help of EMP and LA-ICP-MS analyses allowed us to map its occurrence in terrestrial sections across Kamchatka and to identify this layer in Bering Sea sediment cores at a distance of >600 km from the source. New high-precision 14C dates suggest that the PL2 eruption occurred ~10,200 cal BP, which makes it a valuable isochrone for early Holocene climate fluctuations and permits direct links between terrestrial and marine paleoenvironmental records. The terrestrial and marine 14C dates related to the PL2 tephra have allowed us to estimate an early Holocene reservoir age for the western Bering Sea at 1,410 ± 64 14C years. Another important tephra from the early Holocene eruptive episode of Plosky volcano, coded PL1, was dated at 11,650 cal BP. This marker is the oldest geochemically characterized and dated tephra marker layer in Kamchatka to date and is an important local marker for the Younger Dryas—early Holocene transition. One more tephra from Plosky, coded PL3, can be used as a marker northeast of the source at a distance of ~110 km.

Geochemically fingerprinted widespread tephra layers serve as excellent marker horizons which can directly link and synchronize disparate sedimentary archives and be used for dating various deposits related to climate shifts, faulting events, tsunami, and human occupation. In addition, tephras represent records of explosive volcanic activity and permit assessment of regional ashfall hazard. In this paper we report a detailed Holocene tephrochronological model developed for the Kamchatsky Peninsula region of eastern Kamchatka (NW Pacific) based on ∼2800 new electron microprobe analyses of single glass shards from tephra samples collected in the area as well as on previously published data. Tephra ages are modeled based on a compilation of 223 14C dates, including published dates for Shiveluch proximal tephra sequence and regional marker tephras; new AMS 14C dates; and modeled calibrated ages from the Krutoberegovo key site. The main source volcanoes for tephra in the region are Shiveluch and Kliuchevskoi located 60–100 km to the west. In addition, local tephra sequences contain two tephras from the Plosky volcanic massif and three regional marker tephras from Ksudach and Avachinsky volcanoes located in the Eastern volcanic front of Kamchatka. This tephrochronological framework contributes to the combined history of environmental change, tectonic events, and volcanic impact in the study area and farther afield. This study is another step in the construction of the Kamchatka-wide Holocene tephrochronological framework under the same methodological umbrella. Our dataset provides a research reference for tephra and cryptotephra studies in the northwest Pacific, the Bering Sea, and North America.