Volcanic eruptions from Kamchatka have deposited many unique tephra layers over a large region within the North Pacific, providing important isochrons between key sites such as marine ODP core 883 (Pacific Ocean, Detroit Seamount) and Elgygytgyn Lake (Chukotka, eastern Siberia). Here we present a compilation of C14 dates on major Holocene tephras from the volcanically highly active region, based on decades of detailed stratigraphical fieldwork on Shiveluch, Kliuchevskoy, and other volcanoes.The 12-m thick tephra sequence at the Kliuchevskoy slope has been continuously accumulating during the last ∼11 ka. It contains over 200 visible individual tephra layers and no datable organic material. The section is dominated by dark-gray mafic cinders related to Kliuchevskoy activity. In addition, it contains 30 light-colored thin layers of silicic tephra from distant volcanoes including 11 layers from Shiveluch volcano located only 65 km to the north. We have used EMPA glass analysis to correlate most of the marker tephra layers to their source eruptions dated earlier by C14 (Braitseva et al., 1997; Ponomareva et al., 2007), and in this way linked Kliuchevskoy tephra sequence to sequences at other volcanoes including Shiveluch. The C14 dates and tephras from the northern Kamchatka are then combined into a single Bayesian framework taking into account stratigraphical ordering within and between the sites. This approach has allowed us to enhance the reliability and precision of the estimated ages for the eruptions. Age-depth models are constructed to analyse changes in deposition rates and volcanic activity throughout the Holocene. This detailed chronology of the eruptions serves as a basis for understanding temporal patterns in the eruption sequence and geochemical variations of magmas. This research could prove important for the long-term forecast of eruptions and volcanic hazards.

On Kamchatka, detailed geologic and geomorphologic mapping of young volcanic terrains and observations on historical eruptions reveal that landslides of various scales, from small (0.001 km3) to catastrophic (up to 20–30 km3), are widespread. Moreover, these processes are among the most effective and most rapid geomorphic agents. Of 30 recently active Kamchatka volcanoes, at least 18 have experienced sector collapses, some of them repetitively. The largest sector collapses identified so far on Kamchatka volcanoes, with volumes of 20–30 km3 of resulting debris-avalanche deposits, occurred at Shiveluch and Avachinsky volcanoes in the Late Pleistocene. During the last 10,000 yr the most voluminous sector collapses have occurred on extinct Kamen' (4–6 km3) and active Kambalny (5–10 km3) volcanoes. The largest number of repetitive debris avalanches (> 10 during just the Holocene) has occurred at Shiveluch volcano. Landslides from the volcanoes cut by ring-faults of the large collapse calderas were ubiquitous. Large failures have happened on both mafic and silicic volcanoes, mostly related to volcanic activity. Orientation of collapse craters is controlled by local tectonic stress fields rather than regional fault systems.

Specific features of some debris avalanche deposits are toreva blocks — huge almost intact fragments of volcanic edifices involved in the failure; some have been erroneously mapped as individual volcanoes. One of the largest toreva blocks is Mt. Monastyr' — a ∼ 2 km3 piece of Avachinsky Somma involved in a major sector collapse 30–40 ka BP.

Long-term forecast of sector collapses on Kliuchevskoi, Koriaksky, Young Cone of Avachinsky and some other volcanoes highlights the importance of closer studies of their structure and stability.

Developing chronologies for sediments in the Arctic Ocean and its continental margins is an important but challenging task. Tephrochronology is a promising tool for independent age control for Arctic marine sediments and here we present the results of a cryptotephra study of a Holocene sedimentary record from the Chukchi Sea. Volcanic glass shards were identified and quantified in sediment core HLY0501-01 and geochemically characterized with single-shard electron microprobe and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). This enabled us to reveal a continuous presence of glass shards with identifiable chemical compositions throughout the core. The major input of glasses into the sediments is geochemically fingerprinted to the ∼3.6 ka Aniakchak caldera II eruption (Alaska), which provides an important chronostratigraphic constraint for Holocene marine deposits in the Chukchi-Alaskan region and, potentially, farther away in the western Arctic Ocean. New findings of the Aniakchak II tephra permit a reevaluation of the eruption size and highlight the importance of this tephra as a hemispheric late Holocene marker. Other identified glasses likely originate from the late Pleistocene Dawson and Old Crow tephras while some cannot be correlated to certain eruptions. These are present in most of the analyzed samples, and form a continuous low-concentration background throughout the investigated record. A large proportion of these glasses are likely to have been reworked and brought to the depositional site by currents or other transportation agents, such as sea ice. Overall, our results demonstrate the potential for tephrochronology for improving and developing chronologies for Arctic Ocean marine records, however, at some sites reworking and redistribution of tephra may have a strong impact on the record of primary tephra deposition.

This review is intended to highlight recent exciting advances in the study of distal (>100 km from the source) tephra and cryptotephra deposits and their potential application for volcanology. Geochemical correlations of tephra between proximal and distal locations have extended the geographical distribution of tephra over tens of millions square kilometers. Such correlations embark on the potential to reappraise volume and magnitude estimates of known eruptions. Cryptotephra investigations in marine, lake, and ice-core records also give rise to continuous chronicles of large explosive eruptions many of which were hitherto unknown. Tephra preservation within distal ice sheets and varved lake sediments permit precise dating of parent eruptions and provide new insight into the frequency of eruptions. Recent advances in analytical methods permit an examination of magmatic processes and the evolution of the whole volcanic belts at distances of hundreds and thousands of kilometers from source. Distal tephrochronology has much to offer volcanology and has the potential to significantly contribute to our understanding of sizes, recurrence intervals and geochemical make-up of the large explosive eruptions.

Very few age controls exist for Quaternary deposits over the vast territory of the East Russian Arctic, which hampers dating of major environmental changes in this area and prevents their correlation to climatic changes in the Arctic and Pacific marine domains. We report a newly identified ~177 ka old Rauchua tephra, which has been dispersed over an area of >1,500,000 km2 and directly links terrestrial paleoenvironmental archives from Arctic Siberia with marine cores in the northwest Pacific, thus permitting their synchronization and dating. The Rauchua tephra can help to identify deposits formed in terrestrial and marine environments during the oxygen isotope stage 6.5 warming event. Chemical composition of volcanic glass from the Rauchua tephra points to its island-arc origin, while its spatial distribution singles out the Kamchatka volcanic arc as a source. The Rauchua tephra represents a previously unknown, large (magnitude >6.5) explosive eruption from the Kamchatka volcanic arc.

We report tephrochronological and geochemical data on early Holocene activity from Plosky volcanic massif in the Kliuchevskoi volcanic group, Kamchatka Peninsula. Explosive activity of this volcano lasted for ~1.5 kyr, produced a series of widely dispersed tephra layers, and was followed by profuse low-viscosity lava flows. This eruptive episode started a major reorganization of the volcanic structures in the western part of the Kliuchevskoi volcanic group. An explosive eruption from Plosky (M~6), previously unstudied, produced tephra (coded PL2) of a volume of 10–12 km3 (11–13 Gt), being one of the largest Holocene explosive eruptions in Kamchatka. Characteristic diagnostic features of the PL2 tephra are predominantly vitric sponge-shaped fragments with rare phenocrysts and microlites of plagioclase, olivine and pyroxenes, medium- to high-K basaltic andesitic bulk composition, high-K, high-Al and high-P trachyandesitic glass composition with SiO2 = 57.5–59.5 wt%, K2O = 2.3–2.7 wt%, Al2O3 = 15.8–16.5 wt%, and P2O5 = 0.5–0.7 wt%. Other diagnostic features include a typical subduction-related pattern of incompatible elements, high concentrations of all REE (>10× mantle values), moderate enrichment in LREE (La/Yb ~ 5.3), and non-fractionated mantle-like pattern of LILE. Geochemical fingerprinting of the PL2 tephra with the help of EMP and LA-ICP-MS analyses allowed us to map its occurrence in terrestrial sections across Kamchatka and to identify this layer in Bering Sea sediment cores at a distance of >600 km from the source. New high-precision 14C dates suggest that the PL2 eruption occurred ~10,200 cal BP, which makes it a valuable isochrone for early Holocene climate fluctuations and permits direct links between terrestrial and marine paleoenvironmental records. The terrestrial and marine 14C dates related to the PL2 tephra have allowed us to estimate an early Holocene reservoir age for the western Bering Sea at 1,410 ± 64 14C years. Another important tephra from the early Holocene eruptive episode of Plosky volcano, coded PL1, was dated at 11,650 cal BP. This marker is the oldest geochemically characterized and dated tephra marker layer in Kamchatka to date and is an important local marker for the Younger Dryas—early Holocene transition. One more tephra from Plosky, coded PL3, can be used as a marker northeast of the source at a distance of ~110 km.

Geochemically fingerprinted widespread tephra layers serve as excellent marker horizons which can directly link and synchronize disparate sedimentary archives and be used for dating various deposits related to climate shifts, faulting events, tsunami, and human occupation. In addition, tephras represent records of explosive volcanic activity and permit assessment of regional ashfall hazard. In this paper we report a detailed Holocene tephrochronological model developed for the Kamchatsky Peninsula region of eastern Kamchatka (NW Pacific) based on ∼2800 new electron microprobe analyses of single glass shards from tephra samples collected in the area as well as on previously published data. Tephra ages are modeled based on a compilation of 223 14C dates, including published dates for Shiveluch proximal tephra sequence and regional marker tephras; new AMS 14C dates; and modeled calibrated ages from the Krutoberegovo key site. The main source volcanoes for tephra in the region are Shiveluch and Kliuchevskoi located 60–100 km to the west. In addition, local tephra sequences contain two tephras from the Plosky volcanic massif and three regional marker tephras from Ksudach and Avachinsky volcanoes located in the Eastern volcanic front of Kamchatka. This tephrochronological framework contributes to the combined history of environmental change, tectonic events, and volcanic impact in the study area and farther afield. This study is another step in the construction of the Kamchatka-wide Holocene tephrochronological framework under the same methodological umbrella. Our dataset provides a research reference for tephra and cryptotephra studies in the northwest Pacific, the Bering Sea, and North America.

The ~16-ka-long record of explosive eruptions from Shiveluch volcano (Kamchatka, NW Pacific) is refined using geochemical fingerprinting of tephra and radiocarbon ages. Volcanic glass from 77 prominent Holocene tephras and four Late Glacial tephra packages was analyzed by electron microprobe. Eruption ages were estimated using 113 radiocarbon dates for proximal tephra sequence. These radiocarbon dates were combined with 76 dates for regional Kamchatka marker tephra layers into a single Bayesian framework taking into account the stratigraphic ordering within and between the sites. As a result, we report ~1,700 high-quality glass analyses from Late Glacial–Holocene Shiveluch eruptions of known ages. These define the magmatic evolution of the volcano and provide a reference for correlations with distal fall deposits. Shiveluch tephras represent two major types of magmas, which have been feeding the volcano during the Late Glacial–Holocene time: Baidarny basaltic andesites and Young Shiveluch andesites. Baidarny tephras erupted mostly during the Late Glacial time (~16–12.8 ka BP) but persisted into the Holocene as subordinate admixture to the prevailing Young Shiveluch andesitic tephras (~12.7 ka BP–present). Baidarny basaltic andesite tephras have trachyandesite and trachydacite (SiO2 < 71.5 wt%) glasses. The Young Shiveluch andesite tephras have rhyolitic glasses (SiO2 > 71.5 wt%). Strongly calc-alkaline medium-K characteristics of Shiveluch volcanic glasses along with moderate Cl, CaO and low P2O5 contents permit reliable discrimination of Shiveluch tephras from the majority of other large Holocene tephras of Kamchatka. The Young Shiveluch glasses exhibit wave-like variations in SiO2 contents through time that may reflect alternating periods of high and low frequency/volume of magma supply to deep magma reservoirs beneath the volcano. The compositional variability of Shiveluch glass allows geochemical fingerprinting of individual Shiveluch tephra layers which along with age estimates facilitates their use as a dating tool in paleovolcanological, paleoseismological, paleoenvironmental and archeological studies. Electronic tables accompanying this work offer a tool for statistical correlation of unknown tephras with proximal Shiveluch units taking into account sectors of actual tephra dispersal, eruption size and expected age. Several examples illustrate the effectiveness of the new database. The data are used to assign a few previously enigmatic wide-spread tephras to particular Shiveluch eruptions. Our finding of Shiveluch tephras in sediment cores in the Bering Sea at a distance of ~600 km from the source permits re-assessment of the maximum dispersal distances for Shiveluch tephras and provides links between terrestrial and marine paleoenvironmental records.

Abstract We present new major and trace element, high-precision Sr–Nd–Pb (double spike), and O-isotope data for the whole range of rocks from the Holocene Tolbachik volcanic field in the Central Kamchatka Depression (CKD). The Tolbachik rocks range from high-Mg basalts to low-Mg basaltic trachyandesites. The rocks considered in this paper represent mostly Late Holocene eruptions (using tephrochronological dating), including historic ones in 1941, 1975–1976 and 2012–2013. Major compositional features of the Tolbachik volcanic rocks include the prolonged predominance of one erupted magma type, close association of middle-K primitive and high-K evolved rocks, large variations in incompatible element abundances and ratios but narrow range in isotopic composition. We quantify the conditions of the Tolbachik magma origin and evolution and revise previously proposed models. We conclude that all Tolbachik rocks are genetically related by crystal fractionation of medium-K primary magmas with only a small range in trace element and isotope composition. The primary Tolbachik magmas contain ~ 14 wt. of MgO and ~ 4 wt. of {H2O} and originated by partial melting (~ 6) of moderately depleted mantle peridotite with Indian-MORB-type isotopic composition at temperature of ~ 1250 °C and pressure of ~ 2 GPa. The melting of the mantle wedge was triggered by slab-derived hydrous melts formed at ~ 2.8 {GPa} and ~ 725 °C from a mixture of sediments and MORB- and Meiji-type altered oceanic crust. The primary magmas experienced a complex open-system evolution termed Recharge-Evacuation-Fractional Crystallization (REFC). First the original primary magmas underwent open-system crystal fractionation combined with periodic recharge of the magma chamber with more primitive magma, followed by mixing of both magma types, further fractionation and finally eruption. Evolved high-K basalts, which predominate in the Tolbachik field, and basaltic trachyandesites erupted in 2012–2013 approach steady-state {REFC} liquid compositions at different eruption or replenishment rates. Intermediate rocks, including high-K, high-Mg basalts, are formed by mixing of the evolved and primitive magmas. Evolution of Tolbachik magmas is associated with large fractionation between incompatible trace elements (e.g., Rb/Ba, La/Nb, Ba/Th) and is strongly controlled by the relative difference in partitioning between crystal and liquid phases. The Tolbachik volcanic field shows that open-system scenarios provide more plausible and precise descriptions of long-lived arc magmatic systems than simpler, but often geologically unrealistic, closed-system models.

New and published data on the composition of melt inclusions in olivine (Fo73_yi) from volcanoes of the Kamchatka and northern Kurile Arc are used 1) to evaluate the combined systematics of volatiles (H2O, S, Cl, F) and incompatible trace elements in their parental magmas and mantle sources, 2) to constrain thermal conditions of mantle melting, and 3) to estimate the composition of slab-derived components. We demonstrate that typical Kamchatkan arc-type magmas originate through 5-14% melting of sources similar or slightly more depleted in HFSE (with up to -1 wt.% previous melt extraction) compared to MORB-source mantle, but strongly enriched in H2O,B, Be, Li, Cl. F, LILE, LREE, Th and U. Mean H2O in parental melts f 1.8-2.6 wt.%) decreases with increasing depth to the subducting slab and correlates negatively with both 'fluid-immobile* (e.g. Ti, Na, LREE) and most 'fluid-mobile' (e.g. LILE, S, Cl, F) incompatible elements, implying that solubility in hydrous fluids or amount of water does not directly control the abundance of 'fluid-mobile' incompatible elements. Strong correlation is observed between H2O/Ce and B/Zr (or B/LREE) ratios. Both, calculated H2O in mantle sources (0.1-0.4%) and degrees of melting (5-14%) decrease with increasing depth to the slab indicating that the ultimate source of water in the sub-arc mantle is the subducting oceanic plate and that water flux (together with mantle temperature) governs theextent of mantle melting beneath Kamchatka. A parameterized hydrous melting model [Katzetal. 2003, G3,4(9), 1073] is utilized to estimate that mantle melting beneath Kamchatka occurs at or below the dry peridotite solidus (1245-1330 °C at 1.5-2.0 GPa). Relatively high mantle temperatures (yet lower than beneath back-arc basins and ocean ridges) suggest substantial corner flow driven mantle upwelling beneath Kamchatka in agreement with numerical models implying non-isoviscous mantle wedge rheology. Data from Kamchatka, Mexico and Central America indicate that <5% melting would lake place beneath continental arcs without water flux from the subducting slab. A broad negative correlation appears to exist between crustal thickness and the temperature of magma generation beneath volcanic arcs with larger amounts of decompression melting occurring beneath thinner arc crust (Uihosphere). In agreement with the high mantle temperatures, we observe a systematic change in the composition of slab components with increasing slab depth from solute-poor hydrous fluid beneath the volcanic front to solute-rich hydrous melt or supercritical liquid at deeper depths beneath the rear arc. The solute-rich slab component dominates the budget of LILE, LREE,Th and U in the magmas and originates through wet-melting of subducted sediments and/or altered oceanic crust at > 120 km depth. Melting of the upper parts of subducting plates under water flux from deeper luhosphere (e.g. serpentinites), combined with high .emperatures in the mantie wedge, may be a more common process beneath volcanic arcs than has been previously recognized. 0 2006 Klsevier B.V. All rights reserved.