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H2O and CO2 in parental magmas of Kliuchevskoi volcano inferred from study of melt and fluid inclusions in olivine (2011)
Mironov N.L., Portnyagin M.V. H2O and CO2 in parental magmas of Kliuchevskoi volcano inferred from study of melt and fluid inclusions in olivine // Russian Geology and Geophysics. 2011. V. 52. № 11. P. 1353 - 1367. doi: 10.1016/j.rgg.2011.10.007.    Аннотация
This paper reports new FTIR data on the H2O and CO2 concentrations in glasses of 26 naturally quenched and experimentally partially homogenized melt inclusions in olivine (Fo85–91) phenocrysts from rocks of the Kliuchevskoi volcano. Measured H2O concentrations in the inclusions range from 0.02 to 4 wt.%. The wide variations in the H2O content of the inclusions, which do not correlate with the host olivine composition and contents of major elements in the melts, are explained by the H2O escape from inclusions via diffusion through the host olivine during the magma eruption and the following cooling. The largest H2O loss is characteristic of inclusions from lava samples which cooled slowly after eruption. The minimal H2O loss is observed for inclusions from rapidly quenched pyroclastic rocks. Parental magmas of the Kliuchevskoi volcano are estimated to contain 3.5 wt.% H2O. The new data imply a 40 °C lower mantle temperatures than that estimated earlier for the Kliuchevskoi primary melts. The concentrations of CO2 in glasses range from <0.01 to 0.13 wt.% and do not correlate with the type of studied inclusions and their composition. The calculated pressures of melt equilibria with H2O–CO2 fluid inside the inclusions are lower than 270 MPa. They are significantly lower than a pressure of 500 MPa calculated from the density (~0.8 g/cm3) of cogenetic fluid inclusions in high-Fo olivine. The significant pressure drop inside the melt inclusions after their trapping in olivine might be due to the H2O loss and redistribution of CO2 from melt to daughter fluid phase. Compared with melt inclusions, cogenetic fluid inclusions provide independent information about the crystallization pressures of olivine and initial CO2 content in the Kliuchevskoi magma, which were estimated to be at least 500 MPa and 0.35 wt.%, respectively. The maximum CO2 concentrations in the primary Kliuchevskoi melts are estimated at 0.8–0.9 wt.%. The decompression crystallization of the Kliuchevskoi magmas starts at depths of 30–40 km and proceeds with a continuous decrease in CO2 content and an increase (up to 6–7 wt.%) and then a decrease (at <300 MPa) in H2O content in melts, which explains the origin of the whole spectrum of rocks and melt inclusions of the Kliuchevskoi volcano.
Highly silicic glasses in peridotite xenoliths from Avacha volcano, Kamchatka arc; implications for melting and metasomatism within the sub-arc mantle (2009)
Ishimaru Satoko, Arai Shoji Highly silicic glasses in peridotite xenoliths from Avacha volcano, Kamchatka arc; implications for melting and metasomatism within the sub-arc mantle // Lithos. 2009. V. 107. № 1–2. P. 93 - 106. doi: 10.1016/j.lithos.2008.07.005.    Аннотация
Silicate glasses in peridotite xenoliths from Avacha volcano have high SiO2 (up to 72 wt.) and highly SiO2-oversaturated characteristics; normative quartz content is up to 50 wt.. The glasses represent secondary melts solidified after interaction with mantle peridotite, i.e. crystallization of secondary orthopyroxene at the expense of olivine. We identified two kinds of silicate glasses in Avacha peridotites; one is higher in K2O and enriched in Rb, Ba, U, and Pb than the other. The glasses show basically similar chemical characteristics to the host basaltic andesite to andesite of the Avacha volcano. These chemical characteristics are inherited from slab-derived fluids/melts, which metasomatize the mantle wedge and induce partial melting. The differences of chemical features among the Avacha glasses are attributed to chemical difference of the slab-derived fluids/melts, possibly due to the difference of sediments/basalt ratio of the relevant slab. The low-degree partial melt of peridotite assisted by these fluids/melts, is primarily SiO2-oversaturated, and can conduct silicate metasomatism, evolving through interaction with surrounding mantle peridotite, i.e. formation of orthopyroxene at the expense of olivine. Highly silicic glasses, also reported from peridotite xenoliths from oceanic hotspots and continental rift zones, mostly result from assimilation of orthopyroxene by SiO2-undersaturated melts, which crystallize clinopyroxene and olivine. The glasses also show similar trace-element patterns to their host alkali basaltic magmas, as in the case of arc glasses/calc-alkali magmas. If the glasses in peridotite xenoliths are of silicate metasomatism origin, they are similar in chemistry to host magmas. Reaction between carbonatite melts and peridotites shows the same petrographical feature as that of SiO2-undersaturated silicate melts with peridotites. The glasses originated from carbonatite metasomatism, however, exhibit clearly different trace-element patterns from their host alkali basaltic magmas.
Historical eruptions of Avacha volcano, Kamchatka. Attempt of modern interpretation and classification for long-term prediction of the types and parameters of future eruptions. Part 1 (1737-1909) (1994)
Melekestsev I.V., Braitseva O.A., Dvigalo V.N., Bazanova L.I. Historical eruptions of Avacha volcano, Kamchatka. Attempt of modern interpretation and classification for long-term prediction of the types and parameters of future eruptions. Part 1 (1737-1909) // Volcanology and Seismology. 1994. V. 15. № 6. P. 649-665.    Аннотация
Some of the previous views on the style of the Avacha eruptions during 1737-1909 are revised on the basis of new data obtained by the authors. The types of eruptions, their geological and geomorphological effects, and the related volcanic hazards are reassessed. All eruptions were explosive events, except for the 1894-1895 extrusive-explosive eruption. The eruptions of 1737, 1779, and 1827 are classified as large, the others, as mild or medium-size events. -from Journal summary
http://repo.kscnet.ru/55/ [связанный ресурс]
Historical eruptions of Avacha volcano, Kamchatka. Attempt of modern interpretation and classification for long-term prediction of the types and parameters of future eruptions. Part 2 (1926-1991) (1994)
Melekestsev I.V., Braitseva O.A., Dvigalo V.N., Basanova L.I. Historical eruptions of Avacha volcano, Kamchatka. Attempt of modern interpretation and classification for long-term prediction of the types and parameters of future eruptions. Part 2 (1926-1991) // Volcanology and Seismology. 1994. V. 16. № 2. P. 93-114.    Аннотация
Previous data are summarized and new evidence is presented on the Avacha eruptions of 1926-1927, 1938, and 1945. The last eruption of January 1991 is described. The dynamics of the Avacha eruptive activity is considered for a period of 1737-1991. The eruptions are classified into different types. The type and size of a future event are predicted and the related hazard is assessed. It is recommended that the southwestern and southern sectors of the Avacha surrounding should be declared forbidden for residential or industrial construction because of a high volcanic hazard. -Journal summary
http://repo.kscnet.ru/160/ [связанный ресурс]
Holocene Key-Marker Tephra Layers in Kamchatka, Russia (1997)
Braitseva Olga A., Ponomareva Vera V., Sulerzhitsky Leopold D., Melekestsev Ivan V., Bailey John Holocene Key-Marker Tephra Layers in Kamchatka, Russia // Quaternary Research. 1997. V. 47. № 2. P. 125-139. doi:10.1006/qres.1996.1876.    Аннотация
Detailed tephrochronological studies in Kamchatka Peninsula, Russia, permitted documentation of 24 Holocene key-marker tephra layers related to the largest explosive eruptions from 11 volcanic centers. Each layer was traced for tens to hundreds of kilometers away from the source volcano; its stratigraphic position, area of dispersal, age, characteristic features of grain-size distribution, and chemical and mineral composition confirmed its identification. The most important marker tephra horizons covering a large part of the peninsula are (from north to south; ages given in 14C yr B.P.) SH2(≈1000 yr B.P.) and SH3(≈1400 yr B.P.) from Shiveluch volcano; KZ (≈7500 yr B.P.) from Kizimen volcano; KRM (≈7900 yr B.P.) from Karymsky caldera; KHG (≈7000 yr B.P.) from Khangar volcano; AV1(≈3500 yr B.P.), AV2(≈4000 yr B.P.), AV4(≈5500 yr B.P.), and AV5(≈5600 yr B.P.) from Avachinsky volcano; OP (≈1500 yr B.P.) from the Baraniy Amfiteatr crater at Opala volcano; KHD (≈2800 yr B.P.) from the “maar” at Khodutka volcano; KS1(≈1800 yr B.P.) and KS2(≈6000 yr B.P.) from the Ksudach calderas; KSht3(A.D. 1907) from Shtyubel cone in Ksudach volcanic massif; and KO (≈7700 yr B.P.) from the Kuril Lake-Iliinsky caldera. Tephra layers SH5(≈2600 yr B.P.) from Shiveluch volcano, AV3(≈4500 yr B.P.) from Avachinsky volcano, OPtr(≈4600 yr B.P.) from Opala volcano, KS3(≈6100 yr B.P.) and KS4(≈8800 yr B.P.) from Ksudach calderas, KSht1(≈1100 yr B.P.) from Shtyubel cone, and ZLT (≈4600 yr B.P.) from Iliinsky volcano cover smaller areas and have local stratigraphic value, as do the ash layers from the historically recorded eruptions of Shiveluch (SH1964) and Bezymianny (B1956) volcanoes. The dated tephra layers provide a record of the most voluminous explosive events in Kamchatka during the Holocene and form a tephrochronological timescale for dating and correlating various deposits.
Holocene Volcanoes in Kamchatka (2002)
Holocene Volcanoes in Kamchatka. Institute of Volcanology and Seismology FEB RAS. 2002.
Holocene catastrophic caldera-forming eruptions of Ksudach volcano, Kamchatka (1996)
Melekestsev I.V., Braitseva O.A., Ponomareva V.V., Sulerzhitskiy L.D. Holocene catastrophic caldera-forming eruptions of Ksudach volcano, Kamchatka // Volcanology and Seismology. 1996. V. 17. № 4-5. P. 395-422.    Аннотация
Four Plinian eruptions of Ksudach have been reconstructed and dated by the carbon-14 method. The eruptions produced three collapse calderas: the KS1 eruption formed Caldera V 1700-1800 years ago, the KS2 and KS3 events produced Caldera IV 6000-6100 years ago, and the KS4 eruption formed Caldera III 8700-8800 years ago. The most violent eruption was the KS1 event. The sizes of the calderas were 4 × 6.5 km (V), 5 × 6 km (IV), and presumably 2-3 km across (III). Juvenile material was erupted in a rhythmic manner. The composition of the products was dominated by andesite (KS2 and KS4), dacite and rhyodacite (KS3), and rhyodacite (KS1). It is assumed that all caldera-forming eruptions were triggered by the injection of a new portion of high-temperature basic magma and its mixing with the cooling acid magma of the preexisting source. -from Journal summary

Реконструированы и датированы 14С-методом четыре плинианских извержения вулкана Ксудач, сформировавших три кальдеры обрушения: KCi и кальдеру V - 1700-1800 л. н.; КС2 + КС3 и кальдеру IV - 6000-6100 л. н.; КС4 и кальдеру III 8700-8800 л. н. Самым мощным было извержение KCi: 18-19 км3 пирокластики, высота эруптивной колонны до 23 км. Объем продуктов извержений КС2 + КС3 - 10-11 км3, КС4 - не менее 1,5-1,7 км3. Размеры кальдер: V - 4 X 6,5 км, IV - 5x6 км, поперечь III - предположительно 2-3 км. Вынос ювенильной пирокластики в ходе извержений было ритмичным. Каждый ритм начинался выбросом тефры, а завершался формированием пирокластических потоков. Состав продуктов варьировал от андезитов до риодацитов: КС2 и КС4 - преимущественно андезиты, КС3 - дациты и риодациты, KCi - риодацит. Предполагается, что "спусковой механизм" для начала всех кальдерообразующих извержений - внедрение свежей сильно нагретой магмы основного состава и смешение ее с остывающей кислой магмой существовавшего ранее очага. В соответствии со своими масштабами извержения должны были оказать влияние на климат и озоновый слой 3емли и найти отражение в виде кислотных пиков в Гренландском ледниковом щите.
http://repo.kscnet.ru/903/ [связанный ресурс]
Holocene catastrophic lahars at Avacha and Koryakskiy volcanoes in Kamchatka (1996)
Melekestsev I.V., Sulerzhitskiy L.D., Bazanova L.I., Braitseva O.A., Florenskaya N.I. Holocene catastrophic lahars at Avacha and Koryakskiy volcanoes in Kamchatka // Volcanology and Seismology. 1996. V. 17. № 4-5. P. 561-570.    Аннотация
Remnants of five catastrophic lahars have been discovered, described, and dated by the carbon-14 method. They occurred during eruptions of Avacha (violent explosions with voluminous juvenile pyroclastics) and Koryakskiy (large fissure lava flows): 3500 to 3200 14C years ago or 1900-1500 years B.C. These lahars were much higher in vigor, hazard, and effect on the environment than the lahars generated by the historic eruptions of these volcanoes. -from Journal summary
Holocene eruptive history of Ksudach volcanic massif, South Kamchatka: evolution of a large magmatic chamber (1999)
Volynets O.N., Ponomareva V.V., Braitseva O.A., Melekestsev I.V., Chen Ch.H. Holocene eruptive history of Ksudach volcanic massif, South Kamchatka: evolution of a large magmatic chamber // Journal of Volcanology and Geothermal Research. 1999. V. 91. P. 23-42. doi: 10.1016/S0377-0273(99)00049-9.    Аннотация
The combination of geological, tephrochronological and geochemical studies is used to reconstruct the Holocene eruptive history of Ksudach volcanic massif, South Kamchatka and to trace the evolution of its magma. Ksudach is located in the frontal volcanic zone of Kamchatka. From Early Holocene till AD 240, the volcano had repetitive voluminous caldera-forming eruptions. Later they gave way to frequent moderate explosive–effusive eruptions that formed the Shtyubel' stratovolcano inside the nested calderas, and then to frequent larger explosive eruptions. Holocene eruptive products are low-K2O two pyroxene–plagioclase basaltic andesite to rhyodacite. Mineralogical, geochemical and isotopic data suggest that all the rock varieties originated as a result of fractionation of an initial mafic melt, with insignificant contamination and assimilation. Intensive mixing of the fractionating melts prior to, and during the course of the eruptions, is ubiquitous. The eruptions might have been triggered by repetitive injections of new mafic melt into the silicic chamber. Crystallization of the andesitic and rhyodacitic melts is estimated to have occurred at temperatures of 970–1010°C and 890–910°C, respectively, PH2O 1.5–2.0 kbar and fO2 close to the NNO buffer. According to the experimental data, such PH2O corresponds to 4.5%–5.5% of water in the melt, that is close to the content of water in the silicic hornblende-bearing magmas of the rear zone of the Kuril–Kamchatka arc. Hence, we suggest that the transition from pyroxene phenocryst associations of the frontal zone to the hornblende-bearing ones of the rear zone might be interpreted as reflecting higher temperatures of crystallization of the melts from the frontal zone rather than increasing water content in the rear zone magmas.
http://www.kscnet.ru/ivs/bibl/vulk/ksud/jvgr_ks_99.pdf [связанный ресурс]
Holocene eruptive history of Shiveluch Volcano, Kamchatka Peninsula, Russia (2007)
Ponomareva V., Kyle P., Pevzner M., Sulerzhitsky L., Hartman M. Holocene eruptive history of Shiveluch Volcano, Kamchatka Peninsula, Russia // Geophysical Monograph Series. // Volcanism and Subduction: The Kamchatka Region. 2007. V. 172. P. 263-282. № doi:10.1029/172GM19.    Аннотация
The Holocene eruptive history of Shiveluch volcano, Kamchatka Peninsula, has been reconstructed using geologic mapping, tephrochronology, radiocarbon dating, XRF and microprobe analyses. Eruptions of Shiveluch during the Holocene have occurred with irregular repose times alternating between periods of explosive activity and dome growth. The most intense volcanism, with frequent large and moderate eruptions occurred around 6500–6400 BC, 2250–2000 BC, and 50–650 AD, coincides with the all-Kamchatka peaks of volcanic activity. The current active period started around 900 BC; since then the large and moderate eruptions has been following each other in 50–400 yrs-long intervals. This persistent strong activity can be matched only by the early Holocene one.
Most Shiveluch eruptions during the Holocene produced medium-K, hornblendebearing andesitic material characterized by high MgO (2.3–6.8 wt %), Cr (47–520 ppm), Ni (18–106 ppm) and Sr (471–615 ppm), and low Y (> 18 ppm). Only two mafic tephras erupted about 6500 and 2000 BC, each within the period of most intense activity.
Many past eruptions from Shiveluch were larger and far more hazardous then the historical ones. The largest Holocene eruption occurred ∼1050 AD and yielded >2.5 km3 of tephra. More than 10 debris avalanches took place only in the second half of the Holocene. Extent of Shiveluch tephra falls exceeded 350 km; travel distance of pyroclastic density currents was > 22 km, and that of the debris avalanches ≤20 km.
Holocene volcanism of Northern Kamchatka: The spatiotemporal aspect (2006)
Pevzner M.M. Holocene volcanism of Northern Kamchatka: The spatiotemporal aspect // Doklady Earth Sciences. 2006. Т. 409. № 2. С. 884-887. doi: 10.1134/S1028334X06060109.
http://repo.kscnet.ru/2107/ [связанный ресурс]
How a tectonic earthquake may wake up volcanoes: Stress transfer during the 1996 earthquake–eruption sequence at the Karymsky Volcanic Group, Kamchatka (2007)
Walter Thomas R. How a tectonic earthquake may wake up volcanoes: Stress transfer during the 1996 earthquake–eruption sequence at the Karymsky Volcanic Group, Kamchatka // Earth and Planetary Science Letters. 2007. V. 264. № 3–4. P. 347 - 359. doi: 10.1016/j.epsl.2007.09.006.    Аннотация
A large tectonic earthquake occurred on Kamchatka peninsular on New Year's Day of 1996 along a SW–NE trending fracture system. Just two days after the earthquake and at a distance of about 10–20 km to the north, a simultaneous eruption of two separate volcanoes followed. These were Karymsky Volcano and Akademia Nauk Volcano, the latter having its first eruption in historical records. In this paper I use numerical models in order to elaborate the static stress transfer between the earthquake and the volcanic system during the sequence that culminated in the January 1996 volcano-tectonic events. The models were designed to consider (i) the geodetically identified pre-eruptive period of doming in order to calculate stress changes at the nearby SW–NE trending fracture zone, and (ii) the January 1996 Mw 7.1 earthquake in order to calculate the dilatation and stress changes at the magma plumbing system. The results suggest that stress changes related to year-long inflation under the volcanic centers increased the Coulomb failure stress at the active faults and thus encouraged the earthquake. The earthquake, in turn, prompted dilatation at the magmatic system together with extensional normal stress at intruding N–S trending dikes. Also, field measurements confirmed the presence of N–S oriented fractures above the dike. Unclamping of the N–S oriented fractures allowed magma to propagate and eventually to trigger the twin-eruption at the volcanoes Karymsky and Akademia Nauk. These findings imply that successful hazard evaluations at volcanoes elsewhere require consideration of the seismo-tectonic framework and large earthquake cycles.
Hydrated sub-arc mantle: a source for the Kluchevskoy volcano, Kamchatka/Russia (2000)
Dorendorf Frank, Wiechert Uwe, Wörner Gerhard Hydrated sub-arc mantle: a source for the Kluchevskoy volcano, Kamchatka/Russia // Earth and Planetary Science Letters. 2000. V. 175. № 1–2. P. 69 - 86. doi: 10.1016/S0012-821X(99)00288-5.    Аннотация
Oxygen isotope ratios of olivine and clinopyroxene phenocrysts from the Kluchevskoy volcano in Kamchatka have been studied by CO2 and ArF laser techniques. Measured δ18O values of 5.8–7.1‰ for olivine and 6.2–7.5‰ for clinopyroxene are significantly heavier than typical mantle values and cannot be explained by crustal assimilation or a contribution of oceanic sediments. Positive correlations between δ18O and fluid-mobile elements (Cs, Li, Sr, Rb, Ba, Th, U, LREE, K) and a lack of correlation with fluid-immobile elements (HFSE, HREE) suggest that 18O was introduced into the mantle source by a fluid from subducted altered oceanic basalt. This conclusion is supported by radiogenic isotopes (Sr, Nd, Pb). Mass balance excludes simple fluid-induced mantle melting. Instead, our observations are consistent with melting a mantle wedge which has been hydrated by 18O-rich fluids percolating through the mantle wedge. 18O-enriched fluids are derived from the subducted oceanic crust and the Emperor seamount chain, which is responsible for a particularly high fluid flux. This hydrated mantle wedge was subsequently involved in arc magmatism beneath Kluchevskoy by active intra-arc rifting.
Hydrogen isotope geochemistry and heat balance of a fumarolic system: Kudriavy volcano, Kuriles (2003)
Botcharnikov Roman E., Shmulovich Kirill I., Tkachenko Sergey I., Korzhinsky Mikhail A., Rybin Alexander V. Hydrogen isotope geochemistry and heat balance of a fumarolic system: Kudriavy volcano, Kuriles // Journal of Volcanology and Geothermal Research. 2003. V. 124. № 1-2. P. 45-66. doi:10.1016/S0377-0273(03)00043-X.    Аннотация
The temperature and hydrogen isotope composition of the fumarolic gases have been studied at Kudriavy volcano, Kurile Islands, which is unique for investigating the processes of magma degassing because of the occurrence of numerous easily accessible fumaroles with a temperature range of 100–940°C. There are several local fumarolic fields with a total surface area of about 2600 m2 within the flattened crater of 200×600 m. Each fumarolic field is characterized by the occurrence of high- and low-temperature fumaroles with high gas discharges and steaming areas with lower temperatures. We have studied the thermal budget of the Kudriavy fumarolic system on the basis of the quantitative dependences of the hydrogen isotope ratio (D/H) and tritium concentration on the temperature of fumarolic gases and compared them with the calculated heat balance of mixing between hot magmatic gas and cold meteoric water. Hydrogen isotope composition (δD and 3H) shows a well expressed correlation with the gas temperature. Since D/H ratio and 3H are good indicators of water sources in volcanic areas, it suggests that the thermal budget of the fumarolic system is mostly controlled by the admixing of meteoric waters to magmatic gases. The convective mechanism of heat transfer in the hydrothermal system governs the maximum temperatures of local fumaroles and fumarolic fields. Low-temperature fumaroles at Kudriavy are thermally buffered by the boiling processes of meteoric waters in the mixing zone at pressures of 3–12 bar. These values may correspond to the hydrostatic pressure of water columns about 30–120 m in height in the volcanic edifice and hence to the depth of a mixing/boiling zone. Conductive heat transfer is governed by conductive heat exchange between gases and country rocks and appears to be responsible for the temperature distribution around a local fumarolic vent. The temperature and pressure of shallow degassing magma are estimated to be 1050°C and 2–3 bar, respectively. The length of the ‘main’ fumarolic gas conduit is estimated to be about 80 m from the linear correlation between maximal temperatures of fumarolic fields and distances to the highest-temperature ‘F-940’ fumarole. This value may correspond to the depth of an apical part of the magmatic chamber. The geometry of the crater zone at the Kudriavy summit and the model of convective gas cooling suggest different hydrostatic pressures in the hydrothermal system at the base of high- and low-temperature gas conduits. The depths of gas sources for low-temperature fumaroles are evaluated to be about 200 m at the periphery of the magma chamber.





 

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