Arc magmatism is a product of subduction factory, involving thermal and chemical interactions
between a subducted slab as a material input and mantle wedge as a processing factory. In turn, the
compositions of arc magma provide invaluable information concerning the material input and the
interactions. The northeast Kamchatka Peninsula is an ideal field to examine such interactions and
relationships, being characterized by (1) subduction of the Emperor Seamount Chain (Davaille and
Lees, 2004), and (2) possible material and thermal interaction among the subducted slab, the
overlying mantle wedge and the sub-slab mantle via the edge of subducted Pacific slab (Portnyagin
and Manea, 2008). Within this area, a monogenetic volcanic group occurs along the east coast,
including high-Mg andesitic rocks and relatively primitive basalts (East Cones, EC (Fedorenko,
1969)). We have conducted geochemical studies of the EC lavas, with bulk rock major and trace
elements, and K-Ar and Ar-Ar ages, based on which a possible contribution of subducted seamounts
and its relation to the tectonic setting are discussed.
The elemental compositions indicate that the lavas from individual cones have distinct mantle
sources with different amounts and/or compositions of slab-derived fluids. Based on mass balance,
water content and melting phase relations, we estimate the melting P-T conditions to bet ~1200 ℃
at 1.5 GPa, while the slab surface temperature is 620 –730 ℃ (at 50-80 km depth). Compared with
the southern part of Kamchatka, the slab surface temperature beneath EC seems to be high due to the
thinner Pacific slab associated with the seamount chain and/or the plate rejuvenation from a mantle
plume impact (Davaille and Lees, 2004; Manea and Manea, 2007).
The K-Ar and Ar-Ar ages of the Middle Pleistocene are consistent with the tephrochronological
study (Uspensky and Shapiro, 1984) and the present tectonic setting after 2 Ma (Lander and Shapiro,
2007). The high-Mg andesite with the highest SiO2 content in the EC lavas shows the oldest age
(0.73 ±0.06 Ma) within not only EC but also the northeast part of Kamchatka (e.g., Churikova et
al., 2015, IAVCEI). On the other hand, the rest of EC lava samples show relatively younger ages to
0.18 ±0.07 Ma. These results suggest that the EC lavas including high-Mg andesite and basalt were
generated by mantle flux-melting induced by dehydration of a subducted seamount inheriting a local
thermal anomaly (Nishizawa et al., 2014, JpGU; 2015, JpGU).

Exhalation ore mineralization is developing in the crater part of the active Kudryavy volcano. Lithogeochemical sampling results have revealed that Re, Au, Ag, As, Bi, Cd, Cu, Ge, In, Mo, Pb, S, Sb, Se, Sn, Te, Tl, W, Zn, Rb, and Cs accumulate in solid fumarole formations. These elements are transported by high-temperature volcanic gases and are deposited in mineral phases in the near-surface horizons of fumarole fields under decreasing temperature conditions. The contents of rhenium and other metals in volcanic deposits of fumarole fields locally reach values characteristic of ore deposits. Zoning of lithogeochemical anomalies in ore element associations has been revealed, expressed by the series Re, Mo, W, Au, Cu, Ag, Zn, Cs, Ge → In → Bi, Cd, Pb, Sn, Tl → As, Sb, Se, Te, (Cu, Ag, Au) in the direction from the highest-temperature fumarole fields to less hot, reflecting their temperature zoning. It is demonstrated that lateral geochemical zoning is caused both by the ore element contents in fumarole gases, which depend on temperature, and by differences in the optimal temperature ranges in which various elements precipitate from gases. Signatures for similar exhalation mineral formation processes have been revealed that occurred in the recent geological past at the neighboring extinct Sredny volcano. This suggests the occurrence of similar processes within other volcanic systems of Iturup Island, which increases the prospects for detecting complex exhalation-related manifestations of rare, base, and noble metals.

This study presents data on the geochemical composition of boiling mud pools at the Mutnovsky volcano. The physicochemical characteristics of the pools and the concentrations of major, minor and trace elements in pool solutions vary widely. A comparison of the geochemical compositions of host rocks and solutions indicates that leaching from rocks is not the only source of chemicals in thermal solutions. Geophysical studies reveal the inner structure of thermal fields, which reflect the shapes of the underground reservoirs and feed channels. Using geophysical methods (electrical resistivity tomography and frequency domain investigations), it was shown that the vertical structure and complex geochemical zonation of the feed channels leads to a high contrast in the compositions of the mud solutions. These findings answer questions about the origin and composition of surface manifestations. To elucidate the mechanisms of solution formation, an attempt was made to describe the magmatic fluid evolution and the resulting mixing of waters by physical and mathematical models. The model illustrates fluid migration from a magma chamber to the surface. It is shown that the formation of brines corresponding to the mud pool composition is possible during secondary boiling.

Kamchatka Peninsula is one of the most active volcanic regions in the world. Many Holocene explosive eruptions have resulted in widespread dispersal of tephra-fall
deposits. The largest layers have been mapped and dated by the 14C method. The tephra provide valuable stratigraphic markers that constrain the age of many geological
events (e.g. volcanic eruptions, palaeotsunamis, faulting, and so on). This is the first systematic attempt to use electron microprobe (EMP) analyses of glass to characterize
individual tephra deposits in Kamchatka. Eighty-nine glass samples erupted from 11 volcanoes, representing 27 well-identified Holocene key-marker tephra layers, were analysed. The glass is rhyolitic in 21 tephra, dacitic in two, and multimodal in three.
Two tephra are mixed with glass compositions ranging from andesite/dacite to rhyolite. Tephra from the 11 eruptive centres are distinguished by their glass K2O,
CaO, and FeO contents. In some cases, individual tephra from volcanoes with multiple eruptions cannot be differentiated. Trace element compositions of 64 representative
bulk tephra samples erupted from 10 volcanoes were analysed by instrumental neutron activation analysis (INAA) as a pilot study to further refine the geochemical haracteristics; tephra from these volcanoes can be characterized using Cr and Th contents and La/Yb ratios.
Unidentified tephra collected at the islands of Karaginsky (3), Bering (11), and Attu (5) as well as Uka Bay (1) were correlated to known eruptions. Glass compositions and
trace element data from bulk tephra samples show that the Karaginsky Island and Uka Bay tephra were all erupted from the Shiveluch volcano. The 11 Bering Island tephra
are correlated to Kamchatka eruptions. Five tephra from Attu Island in the Aleutians are tentatively correlated with eruptions from the Avachinsky and Shiveluch volcanoes.

The Klyuchevskaya group of volcanoes (KGV) located in the northern part of Kamchatka has the highest magma production rate for any arc worldwide and several of its volcanoes have been studied in considerable detail [e.g. Kersting & Arculus, 1995; Pineau et al., 1999; Dorendorf et al., 2000; Ozerov, 2000; Churikova et al., 2001, 2012, 2015; Mironov et al., 2001; Portnyagin et al., 2007, 2015; Turner et al., 2007]. However, some volcanoes of the KGV including Late-Pleistocene volcanoes Bolshaya Udina, Malaya Udina, Ostraya Zimina, Ovalnaya Zimina, and Gorny Zub were studied only on a reconnaissance basis [Timerbaeva, 1967; Ermakov, 1977] and the modern geochemical studies have not been carried out at all. Among the volcanoes of KGV these volcanoes are closest to the arc trench and may hold information on geochemical zonation with respect to across arc source variations. We present the first major and trace element data on rocks from these volcanoes as well as on their basement. All rocks are medium-calc-alkaline basaltic andesites to dacites except few low-Mg basalts from Malaya Udina volcano. Phenocrysts are mainly olivine, pyroxene, plagioclase and magnetite, Hb-bearing andesites and dacites are rarely found only in subvolcanic intrusions at Bolshaya Udina volcano. Lavas are geochemically similar to the active Bezymianny volcano, however, individual variations for each volcano exist in both major and trace elements. Trace element geochemistry is typical of island arc volcanism. Compared to KGV lavas all studied rocks form very narrow trends in all major element diagrams, which almost do not overlap with the fields of other KGV volcanoes. The lavas are relatively poor in alkalis, TiO2, P2O5, FeO, Ni, Zr, and enriched in SiO2 compared to other KGV volcanics and show greater geochemical and petrological evidence of magmatic differentiation during shallow crustal processing. Basement samples of the Udinskoe plateau lavas to the east of Bolshaya Udina volcano have similar geochemical composition (trace element enriched high-K basaltic andesites and andesites) and similar eruption age of 274 ka [Calkins et al., 2004] as typical plateau lavas below the northern KGV. This research was supported by RFBR-DFG grant # 16-55-12040.