Abstract—This study is concerned with the petrographic, mineralogic, and geochemical features in the K-high basaltic trachyandesites that were discharged by the 2012–2013 parasitic eruption on Ploskii Tolbachik Volcano. These K-high basaltic trachyandesites exhibit some obvious characteristics that testify to their suprasubduction origin. They are deeply differentiated rocks with strongly fractionated plagioclase.A study of the Sr, Nd, and Pb radiogenic isotope ratios in the K-high basaltic trachyandesites provided evidence of their mantle origin and of the fact that the crust has exerted no influence on their compositions. We performed a comparative analysis of the ratios of the concentrations for some incoherent elements in the K-high basaltic trachyandesites, as well as in intraplate, riftogenic, and island-arc moderate potassium basalts and basaltic andesites in relation to the concentrations of these elements in the primitive mantle. The geochemical features of these K-high basaltic trachyandesites classify them as belonging to the suprasubduction subalkaline formation of the potassium series.

The origin of calc-alkaline high-alumina basalts (HAB) of the Klyuchevskoy volcano, Kamchatka, was examined using electron microprobe analyses of phenocrysts and mineral phases included in the phenocrysts. Continuous trends on major-element variation diagrams suggest the HAB were derived from high-magnesia basalt (HMB) by fractional crystallization. Phenocrysts in the HAB are strongly zoned: olivine (Mg# 91–64), clinopyroxene (Wo45–38En40–51Fs5–20) and chrome—spinel/magnetite inclusions in them (Cr2O3 45–0 wt.%, TiO2 0.5–11%). Microprobe analyses of minerals included in the phenocrysts provide additional constraints on the mineral crystallization trends in the HAB. Fe/Mg partitioning data, when applied to the phenocrysts cores, show they crystallized from a HMB. The similarity of phenocryst core compositions in HAB with those in HMB strongly suggests a genetic relationship between the two magma types.

The Kamchatka volcanic arc (NW Pacific) is one of the most productive arcs in the world, known for its highly explosive activity. At the same time, the Kamchatkan record of late Pleistocene explosive eruptions has remained fragmentary. Here we present the first continuous record of Kamchatkan explosive activity between ~12 and 30 ka, which includes ~70 eruptions and extends the earlier reconstructed Holocene sequence for another 20 ka. Our record is based on geochemical correlations of 14C-dated tephras that represent all Kamchatka volcanic zones and are buried in lacustrine deposits along the 200 km stretch of the Central Kamchatka Depression (CKD). The accompanying geochemical database of volcanic glass compositions includes 3104 new electron microprobe and 221 LA-ICP-MS analyses. The data show that during the period under study, large silicic explosive eruptions peaked at 30e25 ka. Later times were mostly associated with the moderate activity from northern CKD volcanoes Shiveluch and Zarechny. Our tephra record provides the first tephrochronological model for dating and correlating Central Kamchatka late Pleistocene deposits and gives us some insight into the timing of glacial advances in the Kliuchevskoi volcanic group and volcanic response to the onset of the Last Glacial Maximum and glacial unloading at its termination. In addition, studied sections of lacustrine deposits tightly linked by tephra markers suggest the existence of a large lake system within the CKD for ~20 kyr until its final discharge at ~12 ka BP.