Abstract We report petrography, and bulk rock, mineral and glass analyses of eruptive products of the 2012–13 eruption of Tolbachik volcano, Central Kamchatka Depression, Russia. Magmas are shoshonitic in composition, with phenocrysts of olivine and plagioclase; clinopyroxene phenocrysts are scarce. Samples collected as bombs from the active vent, from liquid lava at the active lava front, and as naturally solidified “toothpaste” lava allow us to quantify changes in porosity and crystallinity that took place during 5.25 km of lava flow and during solidification. Olivine-hosted melt inclusions from rapidly-cooled, mm-size tephra have near-constant {H2O} contents (1.19 ± 0.1 wt) over a wide range of {CO2} contents (< 900 ppm), consistent with degassing. The groundmass glasses from tephras lie at the shallow end of this degassing trend with 0.3 wt {H2O} and 50 ppm CO2. The presence of small saturation, rather than shrinkage, bubbles testifies to volatile saturation at the time of entrapment. Calculated saturation pressures are 0.3 to 1.7 kbar, in agreement with the depths of earthquake swarms during November 2012 (0.6 to 7.5 km below the volcano). Melt inclusions from slowly-cooled and hot-collected lavas have {H2O} contents that are lower by an order of magnitude than tephras, despite comparable {CO2} contents. We ascribe this to diffusive {H2O} loss through olivine host crystals during cooling. The absence of shrinkage bubbles in the inclusions accounts for the lack of reduction in dissolved {CO2} (and S and Cl). Melt inclusions from tephras experienced < 3 wt post-entrapment crystallisation. Melt inclusion entrapment temperatures are around 1080 °C. Compared to magmas erupted elsewhere in the Kluchevskoy Group, the 2012–13 Tolbachik magmas appear to derive from an unusually H2O-poor and K2O-rich basaltic parent.

The Holocene eruptive history of Shiveluch volcano, Kamchatka Peninsula, has been reconstructed using geologic mapping, tephrochronology, radiocarbon dating, XRF and microprobe analyses. Eruptions of Shiveluch during the Holocene have occurred with irregular repose times alternating between periods of explosive activity and dome growth. The most intense volcanism, with frequent large and moderate eruptions occurred around 6500–6400 BC, 2250–2000 BC, and 50–650 AD, coincides with the all-Kamchatka peaks of volcanic activity. The current active period started around 900 BC; since then the large and moderate eruptions has been following each other in 50–400 yrs-long intervals. This persistent strong activity can be matched only by the early Holocene one.
Most Shiveluch eruptions during the Holocene produced medium-K, hornblendebearing andesitic material characterized by high MgO (2.3–6.8 wt %), Cr (47–520 ppm), Ni (18–106 ppm) and Sr (471–615 ppm), and low Y (> 18 ppm). Only two mafic tephras erupted about 6500 and 2000 BC, each within the period of most intense activity.
Many past eruptions from Shiveluch were larger and far more hazardous then the historical ones. The largest Holocene eruption occurred ∼1050 AD and yielded >2.5 km3 of tephra. More than 10 debris avalanches took place only in the second half of the Holocene. Extent of Shiveluch tephra falls exceeded 350 km; travel distance of pyroclastic density currents was > 22 km, and that of the debris avalanches ≤20 km.

Late Pleistocene-Holocene volcanism in Kamchatka results from the subduction of the
Pacific Plate under the peninsula and forms three volcanic belts arranged in en echelon manner
from southeast to northwest. The cross-arc extent of recent volcanism exceeds 250 km and
is one of the widest worldwide. All the belts are dominated by mafic rocks. Eruptives with
SiO2>57% constitute ~25% of the most productive Central Kamchatka Depression belt and
~30% of the Eastern volcanic front, but <10% of the least productive Sredinny Range belt.
All the Kamchatka volcanic rocks exhibit typical arc-type signatures and are represented
by basalt-rhyolite series differing in alkalis. Typical Kamchatka arc basalts display a strong
increase in LILE, LREE and HFSE from the front to the back-arc. La/Yb and Nb/Zr increase
from the arc front to the back arc while B/Li and As, Sb, B, Cl and S concentrations decrease.
The initial mantle source below Kamchatka ranges from N-MORB-like in the volcanic front
and Central Kamchatka Depression to more enriched in the back arc. Rocks from the Central
Kamchatka Depression range in 87Sr/86Sr ratios from 0.70334 to 0.70366, but have almost
constant Nd isotopic ratios (143Nd/144Nd 0.51307–0.51312). This correlates with the highest
U/Th ratios in these rocks and suggest the highest fluid-flux in the source region.
Holocene large eruptions and eruptive histories of individual Holocene volcanoes have been
studied with the help of tephrochronology and 14C dating that permits analysis of time-space
patterns of volcanic activity, evolution of the erupted products, and volcanic hazards.

The 7600 14C-year-old Kurile Lake caldera-forming eruption (KO) in southern Kamchatka, Russia, produced a 7-km-wide caldera now mostly filled by the Kurile Lake. The KO eruption has a conservatively estimated tephra volume of 140–170 km3 making it the largest Holocene eruption in the Kurile–Kamchatka volcanic arc and ranking it among the Earth’s largest Holocene explosive eruptions. The eruptive sequence consists of three main units: (I) initial phreatoplinian deposits; (II) plinian fall deposits, and (III) a voluminous and extensive ignimbrite sheet and accompanying surge beds and co-ignimbrite fallout. The KO fall tephra was dispersed over an area of >3 million km2, mostly in a northwest direction. It is a valuable stratigraphic marker for southern Kamchatka, the Sea of Okhotsk, and a large part of the Asia mainland, where it has been identified as a f6 to 0.1 cm thick layer in terrestrial and lake sediments, 1000–1700 km from source. The ignimbrite, which constitutes a significant volume of the KO deposits, extends to the Sea of Okhotsk and the Pacific Ocean on either side of the peninsula, a distance of over 50 km from source. Fine co-ignimbrite ash was likely formed when the ignimbrite entered the sea and could account for the wide dispersal of the KO fall unit. Individual pumice clasts from the fall and surge deposits range from dacite to rhyolite, whereas pumice and scoria clasts in the ignimbrite range from basaltic andesite to rhyolite. Ignimbrite exposed west and south of the caldera is dominantly rhyolite, whereas north, east and southeast of the caldera it has a strong vertical compositional zonation from rhyolite at the base to basaltic andesite in the middle, and back to rhyolite at the top. Following the KO eruption, Iliinsky volcano formed within the northeastern part of the caldera producing basalt to dacite lavas and pyroclastic rocks compositionally related to the KO erupted products. Other post-caldera features include several extrusive domes, which form islands in Kurile Lake, submerged cinder cones and the huge silicic extrusive massif of Dikii Greben’ volcano.

The Kamchatka volcanic arc (NW Pacific) is one of the most productive arcs in the world, known for its highly explosive activity. At the same time, the Kamchatkan record of late Pleistocene explosive eruptions has remained fragmentary. Here we present the first continuous record of Kamchatkan explosive activity between ~12 and 30 ka, which includes ~70 eruptions and extends the earlier reconstructed Holocene sequence for another 20 ka. Our record is based on geochemical correlations of 14C-dated tephras that represent all Kamchatka volcanic zones and are buried in lacustrine deposits along the 200 km stretch of the Central Kamchatka Depression (CKD). The accompanying geochemical database of volcanic glass compositions includes 3104 new electron microprobe and 221 LA-ICP-MS analyses. The data show that during the period under study, large silicic explosive eruptions peaked at 30e25 ka. Later times were mostly associated with the moderate activity from northern CKD volcanoes Shiveluch and Zarechny. Our tephra record provides the first tephrochronological model for dating and correlating Central Kamchatka late Pleistocene deposits and gives us some insight into the timing of glacial advances in the Kliuchevskoi volcanic group and volcanic response to the onset of the Last Glacial Maximum and glacial unloading at its termination. In addition, studied sections of lacustrine deposits tightly linked by tephra markers suggest the existence of a large lake system within the CKD for ~20 kyr until its final discharge at ~12 ka BP.