Simon A., Yogodzinski G.M., Robertson K., Smith E., Selyangin O., Kiryukhin A., Mulcahy S.R., Walker J.D. Evolution and genesis of volcanic rocks from Mutnovsky Volcano, Kamchatka // Journal of Volcanology and Geothermal Research. 2014. V. 286. P. 116 - 137. doi: 10.1016/j.jvolgeores.2014.09.003.
This study presents new geochemical data for Mutnovsky Volcano, located on the volcanic front of the southern portion of the Kamchatka arc. Field relationships show that Mutnovsky Volcano is comprised of four distinct stratocones, which have grown over that past 80 ka. The youngest center, Mutnovsky IV, has produced basalts and basaltic andesites only. The three older centers (Mutnovsky I, II, III) are dominated by basalt and basaltic andesite (60–80 by volume), but each has also produced small volumes of andesite and dacite. Across centers of all ages, Mutnovsky lavas define a tholeiitic igneous series, from 48–70 SiO2. Basalts and basaltic andesites have relatively low K2O and Na2O, and high FeO* and Al2O3 compared to volcanic rocks throughout Kamchatka. The mafic lavas are also depleted in the light rare earth elements (REEs), with chondrite-normalized La/Sm < 1.0. Andesites have generally higher REE abundances and are more enriched in light REEs, some showing negative Eu anomalies. All samples are depleted in field strength elements (HFSEs) relative to similarly incompatible REEs (e.g., low La/Ta, Nd/Hf compared to MORB), similar to island arc volcanic rocks worldwide. Radiogenic isotope ratios (Sr, Nd, Pb, Hf) are similar for samples from all four eruptive centers, and indicate that all samples were produced by melting of a similar source mixture. No clear age-progressive changes are evident in the compositions of Mutnovsky lavas. Mass balance and assimilation-fractional crystallization (AFC) modeling of major and rare earth elements (REEs) indicate that basaltic andesites were produced by FC of plagioclase, clinopyroxene and olivine from a parental basalt, combined with assimilation of a melt composition similar to dacite lavas present at Mutnovsky. This modeling also indicates that andesites were produced by FC of plagioclase from basaltic andesite, combined with assimilation of dacite. Dacites erupted from Mutnovsky I and II have low abundances of REEs, and do not appear to be related to mafic magmas by FC or AFC processes. These dacites are modeled as the products of dehydration partial melting at mid-crustal levels of a garnet-free, amphibole-bearing basaltic rock, which itself formed in the mid-crust by emplacement of magma that originated from the same source as all Mutnovsky magmas. Lead isotope data indicate that subducted sediment is likely present in the source beneath Mutnovsky and most Kamchatka volcanoes, but uniformly radiogenic Hf and Nd in mafic samples (εNd = 8.7–9.3, εHf = 15.4–15.9), and significant variation in trace element ratios at nearly constant εNd and εHf, indicate that sediment plays a minor roll in controlling subduction trace element patterns in Mutnovsky lavas. Mafic lavas with Ba/Th > 450 require an aqueous fluid source component from subducting oceanic crust, but mixing patterns in isotope versus trace element ratio plots for Hf and the REEs (εNd and εHf vs. ratios with Ce, Nd and Hf) demonstrate that a source component with radiogenic Nd and Hf, and fractionated (arc-type) trace element ratios must be present in the source of Mutnovsky lavas. This source component, which is interpreted to be a partial melt of subducted basalt in the eclogite facies (eclogite melt source component), appears to be present in the source of all Kamchatka volcanoes. Cross-arc geochemical patterns at Mutnovsky and in other arc systems (Isu-Bonin, Tonga-Kermadec) suggest that the aqueous fluid component diminishes and the eclogite melt component is increased from volcanoes at the arc front compared to those in rear-arc positions.
Slezin Yu.B. The Bezymyannyi, Shiveluch, and St. Helens volcanoes: A comparative revision of their catastrophic eruptions during the 20th century // Journal of Volcanology and Seismology. 2015. V. 9. № 5. P. 289-294. doi:10.1134/S0742046315050073.
Sorokin A.A., Girina O.A., Korolev S.P., Romanova I.M., Efremov V.Yu., Malkovskii S., Verkhoturov A., Balashov I. The system of computer modeling of ash cloud propagation from Kamchatka volcanoes // 2016 6th International Workshop on Computer Science and Engineering (WCSE 2016). Tokyo, Japan: 2016. V. II. P. 730-733.
Sorokin A.A., Girina O.A., Loupian E.A., Malkovskii S.I., Balashov I.V., Efremov V.Yu., Kramareva L.S., Korolev S.P., Romanova I.M., Simonenko E.V. Satellite observations and numerical simulation results for the comprehensive analysis of ash clouds transport during the explosive eruptions of Kamchatka volcanoes // Russian Meteorology and Hydrology. 2017. V. 42. № 12. P. 759-765. doi: 10.3103/S1068373917120032.
Ash clouds resulting from explosive volcanic eruptions pose a real threat to human (for aircraft flights, airports operations, etc.); therefore, the detection, monitoring, and forecast of their movement is an urgent and important issue. The features and examples of application of the new tool developed on the basis of "Monitoring of active volcanoes of Kamchatka and the Kurile Islands" information system (VolSatView) are described. It allows the integrated monitoring and forecasting of ash cloud transport using the data of remote sensing and mathematical modeling as well as the assessment of the parameters of explosive events.
Sorokin A.A., Korolev S.P., Romanova I.M., Girina O.A., Urmanov I.P. RESTful Web Service for Kamchatka Volcanoes Observations // Modern Information Technologies in Earth Sciences. Proceedings of the International Conference. September 8-13, 2014, Petropavlovsk-Kamchatsky. Vladivostok: Dalnauka. 2014. P. 155
Sorokin A.A., Korolev S.P., Romanova I.M., Girina O.A., Urmanov I.P. The Kamchatka volcano video monitoring system // 2016 6th International Workshop on Computer Science and Engineering (WCSE 2016). Tokyo, Japan: 2016. V. II. P. 734-737.
Taran Yu.A., Hedenquist J.W., Korzhinsky M.A., Tkachenko S.I., Shmulovich K.I. Geochemistry of magmatic gases from Kudryavy volcano, Iturup, Kuril Islands // Geochimica et Cosmochimica Acta. 1995. V. 59. № 9. P. 1749 - 1761. doi: 10.1016/0016-7037(95)00079-F.
Volcanic vapors were collected during 1990–1993 from the summit crater of Kudryavy, a basaltic andesite volcano on Iturup island in the Kuril arc. The highest temperature (700–940°C) fumarolic discharges are water rich (94–98 mole% H2O and have δD values of −20 to −12%o. The chemical and water isotope compositions of the vapors (temperature of thirteen samples, 940 to 130°C) show a simple trend of mixing between hot magmatic fluid and meteoric water; the magmatic parent vapor is similar in composition to altered seawater. The origin of this endmember is not known; it may be connate seawater, or possibly caused by the shallow incorporation of seawater into the magmatic-hydrothermal system. Samples of condensed vapor from 535 to 940°C fumaroles have major element trends indicating contamination by wall-rock particles. However, the enrichment factors (relative to the host rock) of many of the trace elements indicate another source; these elements likely derive from a degassing magma. The strongest temperature dependence is for Re, Mo, W, Cu, and Co; highly volatile elements such as Cl, I, F, Bi, Cd, B, and Br show little temperature dependence. The Re abundance in high-temperature condensates is 2–10 ppb, sufficient to form the pure Re sulfide recently discovered in sublimates of Kudryavy. Anomalously high I concentrations (1–12 ppm) may be caused by magma-marine sediment interaction, as Br/I ratios are similar to those in marine sediments.
The high-temperature (>700°C) fumaroles have a relatively constant composition (∼2 mol% each C and S species, with SO2/H2S ratio of about 3:1, and 0.5 mol% HCl); as temperature decreases, both St and CI are depleted, most likely due to formation of native S and HCl absorption by condensed liquid, in addition to the dilution by meteoric water. Thermochemical evaluation of the high-temperature gas compositions indicates they are close to equilibrium mixtures, apart from minor loss of H2O and oxidation of CO and H2 during sampling. Calculation to an assumed equilibrium state indicates temperatures from 705 to 987°C. At high temperature (≈900°C), the redox states are close to the overlap of mineral (quartz-fayalite-magnetite and nickel-nickel oxide) and gas (H2OH2SO2H2S) buffer curves, due to heterogeneous reaction between the melt and gas species. At lower temperatures (<800°C), the trend of the redox state is similar to the gas buffer curve, probably caused by homogeneous reaction among gas species in a closed system during vapor ascent.
Taran Yu.A., Pilipenko V.P., Rozhkov A.M., Vakin E.A. A geochemical model for fumaroles of the Mutnovsky volcano, Kamchatka, USSR // Journal of Volcanology and Geothermal Research. 1992. V. 49. № 3–4. P. 269 - 283. doi: 10.1016/0377-0273(92)90018-9.
On the basis of the chemical, isotopic and thermodynamic characteristics of fluids sampled between 1964 and 1989 a genetic model description is given for fumaroles of the Mutnovsky volcano. There are three individual groups of fumaroles in the Mutnovsky crater which show stable activity for a long period of time: “the Active Funnel” (temperatures exceed 600°C), the “Upper Field” (up to 320°C) and the “Bottom Field” (from 100 to 150°C). The three principal zones of emission have different gas composition, water isotopic composition, radioactivity and 3He/4He ratios. The abundance of magmatic components in the high-temperature fumaroles of the “Active Funnel” is much higher than those in gases from the other groups. Emission rate of SO2 from the “Active Funnel” is about 200 t/d, which requires complete degassing as a minimum of 1 km3 of magma every 20 years. Fluids of the “Upper Field” contain up to 80% of steam from the Mutnovsky geothermal system. Temperature variations of the “Bottom Field” fumaroles (from 97°C before 1982 to 151°C in 1989) result from changes in hydrological conditions in the crater. Evaporation of high-saline acid brine which is formed in the interior of the volcano is responsible for the composition of the “Bottom Field” gas-steam discharges.